Optimizing Millisecond Time Scale Near-Infrared Emission in Polynuclear Chrome(III)–Lanthanide(III) Complexes
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Metal organic supramolecular chemistry on surfaces has matured to a point where its underlying growth mechanisms are well understood and structures of defined coordination environments of metal atoms can be synthesized in a controlled and reproducible proc ...
Because of their remarkable and unmatched optical and magnetic properties, the lanthanides are under the limelight when it comes to high technology. These elements are used in strategic applications such as optical glasses and lasers, telecommunications, l ...
A new class of benzimidazole-substituted 8-hydroxyquinoline ligands has been prepared that contain a monoanionic tridentate N,N,O-coordinating unit. These ligands form charge-neutral lanthanide complexes of the type [Ln(LR) 3] · nH2O or [Ln2(L2)3] · nH2O ( ...
The syntheses, structures, and magnetic properties of four new complex salts, (PPN){Mn-III(salphen)(MeOH)[M-III(CN)(6)]} 7MeOH (Mn2M 7MeOH) (M = Fe, Ru, Os and Co; PPN+ = bis(triphenylphosphoranylidene)ammonium cation; H2salphen = N,N'-bis(salicyliden ...
The photophysics and photochemistry of transition metal complexes (TMCs) has long been a hot field of interdisciplinary research. Rich metal-based redox processes, together with a high variety in electronic configurations and excited-state dynamics, have r ...
In light of the already proven applications of transition-metal (TM) oxide clusters, including catalysis, selective sorption, sepns., mol. recognition, environmental decontamination, and nanotechnol., one can imagine that the development of framework mater ...
In attempts to synthesize compds. contg. mixed lanthanide and transition metal oxide magnetic nanostructures, a new 3d-4f arsenate phase, Na3GdMn3O3(AsO4)3, was isolated using high-temp., molten-salt methods. The X-ray single-crystal structure anal. shows ...
Total halide abstraction from LnCl3 by Ag[Al(OC(CF3)3)4]/CH3CN has been confirmed for a series of lanthanide metal ions by the structural characterization of [Ln(CH3CN)n][Al(OC(CF3)3)4]3 (n = 9, Ln3+ = Nd, Eu, Gd, Dy; n = 8, Ln3+ = Tm) complexes. Evidence ...
Transition-metal catalyzed C-H functionalizations became a complementary and efficient bond-forming strategy over the past decade. In this respect, Cp*Rh(III) complexes have emerged as powerful catalysts for a broad spectrum of reactions giving access to s ...
Hybrid solids, made of chem. dissimilar components, have drawn much interest in advanced materials synthesis due to their structural versatility and multifunctional properties. For example, metal-org. frameworks (MOFs) have been extensively explored for th ...