The Role of Site-Specific Hydrogen Bonding Interactions in the Solvation Dynamics of N-Acetyltryptophanamide
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Bromide promoted decompn. of tert-Bu bromide in the presence of triphenylphosphine gives, besides isobutene, hydrogen(triphenyl)phosphonium bromide. When heated to approx. 150 DegC in the presence of xylene, the latter salt liberates hydrogen bromide which ...
Upon treatment with Lewis bases Do (Do = pyridine bases or THF), the Lewis acids tmp2AlX (X = Cl, Br, I) are converted exclusively to the monoadducts tmp2AlX.Do. Crystal and mol. structure of these monoadducts were detd. The Al-X bonds of these addn. compd ...
Hydrophobic liq. salts of formula (I) are new: R1,R3 = 1-8C (un)branched alkyl, fluoroalkyl, or alkoxyalkyl; R2,R4,R5 = H or 1-3C alkyl. Also claimed is: (a) the prepn. of such salts; (b) an electrolytic compsn. contg. (I) as aprotic polar solvent; and (c) ...
(Asulab S.A., Switz.; Hydro Quebec; Centre National Dela Recherche Scientifique (CNRS)).1996
1,4-Dienes, vinyl ethers, allyl ethers, allyl thio ethers, and propenethiolates were metalated by BuLi in the presence of an activator such as KOCMe3. Since the solvent, the counter-ion, or the temp. may be varied before subsequent treatment with an electr ...
Railway ballast provides both the foundation and drainage for railway track. It can become heavily contaminated with diesel fuel due to leakage and spillage. Typical analytical methods for soils may not be applicable to the assessment of ballast. The effic ...
An Ugi reaction promoted by ammonium chloride in aprotic solvent is documented here for the first time. From readily accessible starting materials, macrocycles with an endo aryl-aryl ether bond are synthesized in only two steps, Ugi four-component reaction ...
