Single-nanowire solar cells beyond the Shockley-Queisser limit

Light management is of great importance in photovoltaic cells, as it determines the fraction of incident light entering the device. An optimal p-n junction combined with optimal light absorption can lead to a solar cell efficiency above the Shockley-Queisser limit. Here, we show how this is possible by studying photocurrent generation for a single core-shell p-i-n junction GaAs nanowire solar cell grown on a silicon substrate. At 1 sun illumination, a short-circuit current of 180 mA cm(-2) is obtained, which is more than one order of magnitude higher than that predicted from the Lambert-Beer law. The enhanced light absorption is shown to be due to a light-concentrating property of the standing nanowire, as shown by photocurrent maps of the device. The results imply new limits for the maximum efficiency obtainable with III-V based nanowire solar cells under 1 sun illumination.

Nanoscale Organic / Inorganic Hybrid Photovoltaic Devices

Thomas Dufaux

There is an increasing trend of using various types of nanostructures as components of solar cells. This highlights the need to gain a deeper understanding of the nanoscale interface in such devices. The present thesis aims to study individual photoactive junctions as the elementary functional unit of bulk photovoltaic devices, and exploit the gained knowledge toward further improving the solar cells' efficiency. Along this direction, Schottky-contacts to cadmium sulphide nanowires were thoroughly studied using scanning photocurrent microscopy (SPCM). In conjunction with theoretical simulations of the measured photocurrent profiles, it was found that charge carriers can be very efficiently extracted out of a few micrometer long nanowire segments below the metal contact. Moreover, the carrier combination rate in this section could be determined as a function of an applied bias or backgate voltage. These findings provide valuable clues about how electric fields are distributed within semiconductor nanowire-based devices. Moreover, SPCM was employed to explore the local photoresponse along graphene/CdS heterojunctions, representing a first step toward implementing graphene as an active acceptor material into solar cells. The short circuit current of such devices could be enhanced by two orders of magnitudes through chemical tailoring of the graphene-CdS interface. In addition, evidence was obtained that surface plasmon excitation in the metal contacts can make significant contributions to the generated photocurrent. This effect was exploited in the fabrication of novel surface plasmon detectors, which support different plasmon modes depending on the polarization direction of the incoming light. Finally, it was attempted to realize photovoltaic devices comprising a pn-junction implemented into a π-conjugated organic polymer. While the electric-field assisted exciton dissociation in this system could be successfully modelled in the framework of the Braun-Onsager model, photoinduced charge separation at the interface between differently gated regions of the polymer could not be achieved due to insufficient electron conduction of the material.

EPFL2012

Increasing efficiency of perovskite solar cells using low concentrating photovoltaic systems

Hasan Baig, Hiroyuki Kanda, Mohammad Khaja Nazeeruddin

Perovskite solar cell (PSC) technology is the flag bearer for the future of photovoltaics allowing unlimited possibilities for its application. This technology is currently limited by issues related to its scale-up, stability and the composition of the materials used in its preparation. Using small sized solar cells with higher efficiency under solar concentration is gaining traction as a methodology for scaling up this technology and broadening its applications. However, this has only been reported in devices with size

2020

Strategies to Optimizing Dye-Sensitized Solar Cells

Sophie Wenger

Dye-sensitized solar cells (DSCs) constitute a novel class of hybrid organic-inorganic solar cells. At the heart of the device is a mesoporous film of titanium dioxide (TiO2) nanoparticles, which are coated with a monolayer of dye sensitive to the visible region of the solar spectrum. The role of the dye is similar to the role of chlorophyll in plants; it harvests solar light and transfers the energy via electron transfer to a suitable material (here TiO2) to produce electricity — as opposed to chemical energy in plants. DSCs are fabricated of abundant and cheap materials using inexpensive processes (e.g. screen-printing) and are likely to be a significant contributor to the future commercial photovoltaic technology portfolio. The work conducted during this thesis aimed at optimizing the DSC using three different strategies: The use of versatile organic sensitizers for stable and efficient DSCs, the study of tandem device architectures in combination with other solar cells to harvest a larger fraction of the solar spectrum, and the development of a validated optoelectric model of the DSC. Organic donor-π-acceptor dyes are an interesting alternative to the standard metal-organic complexes used in DSCs. Efficient photovoltaic conversion and stable performance could be demonstrated with three classes of donor systems, namely diphenylamine, difluorenylaminophenyl, and π-extended tetrathiafulvalene. The highest conversion efficiencies were obtained with a difluorenylaminophenyl donor system (η = 8.3 % with a volatile electrolyte and η = 7.6 % with a solvent-free ionic liquid, which was a new record for organic dyes at the time of publication). Surprisingly, efficient regeneration of the oxidized dye by the I-/I3- redox mediator was found with the π-extended tetrathiafulvalene system, even though the thermodynamic driving force was as low as 150 mV. So far driving forces of 300-500 mV had been regarded as necessary for efficient regeneration of the dye cation. Also, important structure-property relationships pertaining to the recombination of electrons with the electrolyte and to the stability of the device could be identified (i.e. effect of linear vs. branched structure, linker length, and moieties used). The power conversion efficiency of solar cells can be extended beyond the limit for a single cell (∼ 30 %) by using multiple cells with different optical gaps in a tandem device. DSCs and chalcopyrite Cu(In,Ga)Se2 (CIGS) solar cells have complementary optical gaps and are thus suitable systems for integration in a tandem device. It was shown that a monolithic DSC/CIGS tandem device has the potential for increased efficiency over a mechanically stacked device due to increased light transmission to the bottom cell, and a monolithic DSC/CIGS device with an initial efficiency of η = 12.2 % was demonstrated. The degradation of the devices — induced by the corrosion of the CIGS cell in contact with the I-/I3- redox mediator — could be retarded with a protective thin conformal ZnO/TiO2 oxide layer coated on the CIGS cell by atomic layer deposition. Finally, an experimentally validated optical and electrical model of the DSC has been developed to assist the optimization process, which is predominantly conducted by empirical means in the DSC research community. The optical model allows to accurately calculate the internal quantum efficiency of devices, i.e. the ratio of extracted electrons to absorbed photons by the dye, a crucial and so far difficult to determine characteristic. Intrinsic parameters — like injection efficiency, electron diffusion length, or distribution of trap states in the TiO2 — can be extracted from experimental steady-state and time-dependent data with the electric model. The model allows to make a comprehensive and quantitative loss analysis of the different optical and electric loss channels in the DSC. The model has been implemented with a graphical user interface for straightforward usage. All three optimization strategies — organic dyes, tandem architecture, and device modeling — developed during this thesis make a valuable contribution to the development and commercialization of inexpensive and high efficiency DSCs. They enable a comprehensive view of the system and pave the way for a systematic analysis and reduction of losses, which has been the ultimate route to success for several established photovoltaic technologies.