Dynamic Studies through Control of Relaxation in NMR Spectroscopy
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It is shown how amplitude-modulated radio-frequency pulses optimized for selective inversion of magnetization can be applied to static powder samples with inhomogeneously broadened spectra. Selective one-dimensional methods can in principle provide informa ...
This method measures cross relaxation rates in highly resolving NMR spectroscopy, where the sample substance is dissolved in a liq. and has nuclei A and X which have different chem. shifts WA and WX in a homogeneous static magnetic field Bo in the directio ...
In crowded NMR spectra, it is shown how longitudinal relaxation rates (lab.-frame rates 1/T1) can be measured by selective inversion-recovery of a chosen site A followed by selective transfer of magnetization to another site X through a scalar coupling JAX ...
The internuclear distance between two homonuclear dipolar-coupled dil. spins-1/2, SA and SX, can be measured by rotational resonance expts. in solid state NMR. These involve rotating the sample at the magic angle while fulfilling the condition for rotation ...
New exptl. methods are presented that allow one to measure cross-correlation between the fluctuations of dipolar interactions and chem. shift anisotropy (CSA) in scalar coupled systems with two and three spins I = 1/2 in isotropic soln. The methods involve ...
In order to sep. overlapping diagonal multiplets in two- or three-dimensional NMR spectra, new sequences using selective pulses are described which allow one to "inject" magnetization at the beginning of the evolution period by transfer from a selected cou ...
A SPLIT-COSY (SPLIT = sepn. of patterns by lifting of the imbroglio of transfer) technique is proposed for the sepn. of overlapping multiplets in the signal-rich region of a COSY spectra. This technique is particularly suitable for isomeric mixts. Results ...
New NMR techniques are described for transferring transverse magnetization between scalar-coupled nuclei in the rotating frame. The methods involve simultaneous spin-locking of two selected spins A and X, using cosinusoidal modulation of the radio frequenc ...
Dipolar-coupled spectra of mols. dissolved in liq. cryst. solvents were analyzed by applying pattern recognition procedures to 2-dimensional z-filtered correlation spectra (z-COSY). Transitions that share common common energy levels can be recognized as su ...
A novel spin-echo expt. is proposed that uses semiselective Gaussian pulse cascades for refocusing in systems with homonuclear couplings. The expt. allows one to obtain evdience of differential T2 effects due to cross-correlation of proton chem. shift anis ...
