NMR investigation of the low-temperature dynamics of solid He-4 doped with He-3 impurities
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We investigate the spin relaxation of negatively charged excitons in modulation-doped CdTe quantum wells by time-resolved photoluminescence. The charged exciton spin flip process is found to be very sensitive to the excitation energy but not to a change of ...
The temp. dependence of NMR relaxation rates was investigated for the backbone of 15N/13C labeled human ubiquitin in the temp. range of 20-50 DegC. The 15N autorelaxation rates give evidence that the potential energy functions for 15N-HN bonds are not quad ...
A spectrometer allowing the measurement of signals with spin-spin relaxation times as short as 0.5 μs has been developed. It consists of a transmitter based on a commercial spectrometer and a homemade receiver. The acquired signals are imported in the soft ...
A detailed analysis of nitrogen-15 longitudinal relaxation times in microcrystalline proteins is presented. A theoretical model to quantitatively interpret relaxation times is developed in terms of motional amplitude and characteristic time scale. Differen ...
Internal motions in proteins, such as oscillations of internuclear vectors u(NiHiN) of amide bonds about their equil. position, can be characterized by a local order parameter. This dynamic parameter can be detd. exptl. by measuring the longitudinal and tr ...
In my thesis I shall focus on the development of new NMR experimental methods to study structure and internal motions of two kinds of biological polymers, viz. proteins and nucleic acids. I shall investigate the anisotropic local motions of peptide planes ...
We performed an Eu153 and Eu151 NMR study of EuO and Gd doped EuO using a home-made spectrometer designed to measure signals with fast spin-spin relaxation times. We determined and described the broadening mechanisms giving rise to the structure in the lin ...
A new method for selective excitation in biomol. NMR uses two-fold single-transition cross-polarization between protons and nitrogen-15 or carbon-13 nuclei. Switching the frequencies between the forward and backward transfer steps allows one to select a mu ...
Nuclear spin-lattice relaxation measurements were performed on Co-based magnetic nanowires, in zero field and in 1 T applied field. A measurement method is developped that allows a confident interpretation of the experimental data. An enhanced relaxation d ...
Several methods are presented for the selective determination of spin-lattice and spin-spin relaxation rates of backbone protons in labeled proteins. The relaxation rates of amide protons in (15)N labeled proteins can be measured by using two-way selective ...