Bromate catalytic reduction in continuous mode using metal catalysts supported on monoliths coated with carbon nanofibers
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Transition-metal-catalyzed hydrosilylation of olefins is one of the most important methods for the preparation of organosilicon compounds, which have broad applications in both synthetic and material chemistry. For decades, precious metals, principally pla ...
CROCUS is a teaching and research zero-power reactor operated by the Laboratory for Reactor Physics and Systems Behaviour (LRS) at the Swiss Federal Institute of Technology (EPFL). Three new experimental programmes are scheduled for the forthcoming years. ...
Catalyst design for selective hydrogenations is of major importance for the manufacturing of fine chemicals. Catalytic procedure which uses scarce and expensive noble metals is very challenging in terms of exclusive attack of a single functionality or subs ...
The first efficient and non-precious nanoparticle catalyst for alkene hydrosilylation with commercially relevant tertiary silanes has been developed. The nickel nanoparticle catalyst was prepared in situ from a simple nickel alkoxide precatalyst Ni((OBu)-B ...
The possibility to increase the performance (productivity or selectivity) of a chemical reactor by using periodic variations of reaction parameters (e.g. reactant concentration or temperature) has been theoretically envisaged since the beginning of the 70t ...
Gas cooling in nuclear power plants (NPPs) has a long history, the corresponding reactor types developed in France, the UK and the US having been thermal neutron-spectrum systems using graphite as the moderator. The majority of NPPs worldwide, however, are ...
The objective of this thesis is the development of a compact reactor for continuous three-phase reactions in single-pass configurations. The design is based on a bubble column reactor staged with layers of catalytic material. To make the reactor suitable f ...
The use of zeolites for catalytic reactions is a field in continuous development. Since it was demonstrated that metal-zeolites are efficient catalysts for NOx abatement, decomposition of nitrous oxide (N2O) over Fe-containing zeolites has attracted great ...
The aim of this work is to study the activity of new Pd catalysts, supported on two different nano structured carbon materials, for bromate catalytic hydrogenation. The influence of the support has been studied, obtaining the best results with a palladium ...
N2O decomposition to gaseous N-2 and O-2 catalyzed by a commercial Fe-ZSM-5 has been studied by different transient techniques: (i) via the transient response methods at ambient pressure, (ii) via the temporal analysis of products (TAP) reactor under vacuu ...