The use of Pd catalysts on carbon-based structured materials for the catalytic hydrogenation of bromates in different types of water
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With increasing emphasis placed on cleaner chemical synthesis, energy efficiency and waste minimisation, the manufacture of pharmaceuticals and fine chemicals is undergoing a progressive shift from conventional stoichiometric organic processes to a harness ...
The gas phase (1 atm, 453 K) hydrogenation of p-chloronitrobenzene (p-CNB) over a series of laboratory-synthesized and commercial Pd (1-10% wt) supported on activated carbon (AC) and non-reducible (SiO2 and Al2O3) and reducible (ZnO) oxides has been examin ...
The direct functionalization of carbon-hydrogen bonds is an emerging tool to establish more sustainable and efficient synthetic methods. We present its implementation in a cascade reaction that provides a rapid assembly of functionalized indanylamines from ...
Nitrogen-doped and un-doped carbon nanofibers layers, denoted as N-CNFs and CNFs respectively, coating the walls of cordierite monoliths have been used as support for Pd and Ru catalyst. They have been tested in bromate reduction in batch and continuous op ...
Bimetallic (Pd-Cu, Pd-Sn) nanoparticles supported on structured fibrous carbons (activated carbon fibers and carbon nanofibers grown on sintered metal fibers) were tested in nitrate removal of natural polluted water by hydrogen (a batch and continuous mode ...
Traditionally, the search for active and selective catalysts involved a rather tedious "hit-and-miss" approach in which hundreds, if not thousands catalysts were tested until the optimal substance was identified. With the advancing theoretical understandin ...
Transition-metal-catalyzed C-H functionalizations have emerged as complementary and powerful tools to access molecular complexity from widely available starting materials. Herein, we present a strategy for asymmetric intramolecular Pd(0)-catalyzed C-H func ...
We present 100?% selectivity to p-chloroaniline through the continuous gas-phase (atmospheric pressure; T=393523 K) catalytic hydrogenation of p-chloronitrobenzene over an activated Cu?Al (molar Cu/Al ratio 3:1) hydrotalcite. The synthesis by continuous co ...
Nanostructured C-based catalysts have been developed to be used in continuously operated (open-flow) reactors for the removal of bromates and nitrates from polluted water. The catalysts contain transition-metal (Pd, Cu, and Sn) nanoparticles (NPs) supporte ...