Synthesis, Characterization, and Reactivity of the First Osmium beta-Diketiminato Complexes and Application in Catalysis
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The industrial production of aromatic amines, essential intermediates for the synthesis of several drugs, dyes, pigments and agrochemicals, requires the use of heterogeneous catalysis. These molecules were formerly produced by the Béchamp reduction, a non- ...
Catalyst design for selective hydrogenations is of major importance for the manufacturing of fine chemicals. Catalytic procedure which uses scarce and expensive noble metals is very challenging in terms of exclusive attack of a single functionality or subs ...
The redox chemistry of f-elements is drawing the attention of inorganic chemists due to their unusual reaction pathways. Notably low-valent f-element complexes have been shown to be able to activate small molecules such as CO2 and N2 in mild conditions. Co ...
A hypervelocity (6.7–7.0 km/s) impact testing campaign was conducted using Ø 2 mm, 95% Al projectiles onto A357 aluminium alloy stochastic foams with 4–5 mm typical pore dimensions, or alternatively diamond cubic periodic structures of cast AlSi12 with a 6 ...
Metal organic supramolecular chemistry on surfaces has matured to a point where its underlying growth mechanisms are well understood and structures of defined coordination environments of metal atoms can be synthesized in a controlled and reproducible proc ...
Moiré effects appear when two sets of periodic structures are superimposed. By combining advanced micro-fabrication technologies and the moiré theory, we are able to obtain visually appealing moirés. Specific metallic patterns are created on one side of a ...
We described herein a simple approach for N-formylation with CO2 and hydrosilane reducing agents. Fluoride and hydroxide salts efficiently catalyzed the reaction, principally through activation of the hydrosilanes, which led to hydrosilane reactivities com ...
Rivers in mountainous areas are subject to cyclic perturbations due for instance to summer storms or daily variations in snowmelt. Such phenomena cause successive floods occurring under very similar forcing conditions. However, as shown by several field st ...