Experimental study and thermodynamic description of the Au-Cu-Ge system
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By combining methods of kinetic and density functional theory, we present a description of molecular fluids which accounts for their microscopic structure and thermodynamic properties as well as their hydrodynamic behavior. We focus on the evolution of the ...
Thermodynamic analysis of metabolic networks has recently generated increasing interest for its ability to add constraints on metabolic network operation, and to combine metabolic fluxes and metabolite measurements in a mechanistic manner. Concepts for the ...
We discuss the problem of full counting statistics for periodic pumping. The probability generating function is usually defined on a circle of the "physical" values of the counting parameter, with its periodicity corresponding to charge quantization. The e ...
We consider an elastic chain at thermodynamic equilibrium with a heat bath, and derive an approximation to the probability density function, or pdf, governing the relative location and orientation of the two ends of the chain. Our motivation is to exploit ...
Our work investigates the precipitation mechanism of a seeded calcium carbonate reaction, by using cryogenic TEM to observe the early stages of the reaction. The early precipitation of a hydrated phase is proposed as an intermediate phase before transforma ...
Numerical calculations of the evaporation kinetics of bulk volatile liquids and of water from smectite clay granules are compared with experimental results. The weight loss of the volatiles is analyzed by thermogravimetry and differential calorimetry. Unde ...
The ion pair of the stereolabile C3-symmetric, i+o proton complex [1⋅H]+ of diaza-macropentacycle 1 and the configurationally stable Δ-TRISPHAT ([Δ-3]−) anion exists in the form of two diastereomers, namely, [Δ-(1⋅H)][Δ-3] and [Λ-(1⋅H)][Δ-3], the ratio of ...
The magnetic entropy variation for the ordered spin-ice Tb2Sn2O7 and the spin-liquid Tb2Ti2O7 measured up to similar to 20 K shows that the crystal-field ground state for both systems is a singlet split from the first excited level by a thermal energy of s ...
We present a theoretical framework for the thermodynamic properties of supercoiling-induced denaturation bubbles in circular double-stranded DNA molecules. We explore how DNA supercoiling, ambient salt concentration, and sequence heterogeneity impact on th ...
In the prospect of reducing the greenhouse gas emissions contributing to the global warming the study of CO2 capturing processes is essential. The purpose of this project would be to study more in detail the chemical absorption with amines for CO2 separati ...