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Thermodynamic modeling is a versatile tool for predicting the chemical composition cement during the hydration of cement. The quality of the thermodynamic modeling depends directly on the quality and completeness of thermodynamic database used. One of the ...
The modeling platform µic has been extended to study the hydration of cement based systems. It is shown that the hydration kinetics of alite can be described through the implementation of two mechanisms: a solution controlled dissolution (SCD) mechanism fo ...
The content of individual amorphous supplementary cementitious materials (SCMs) in anhydrous and hydrated blended cements was quantified by the PONKCS [1] X-ray diffraction (XRD) method. The analytical precision and accuracy of the method were assessed thr ...
This thesis investigates the replacement of Portland cement by addition of high amounts of calcined clays and limestone. Such ternary blends can become more ecological and economical binders to answer the worldwide housing shortage. It could be demonstrate ...
High-performance concrete is sensitive to early-age cracking, mainly due to its rapidly-developing autogenous shrinkage. Autogenous shrinkage and internal relative humidity (RH) decrease are direct consequences of the emptying of capillary pores due to cem ...
This paper describes a macroscopic model of the chemo-thermo-poromechanical behaviour of a hydrating cement paste. The hydrating cement is viewed as an open hardening porous medium. The increments of elastic and viscoelastic strain, pore pressure, temperat ...
Some of the limitations of the model recently used by Nicoleau in a recent article [Accelerated growth of calcium silicate hydrates: experiments and simulations, Cement Concr. Res. 21 (2011) 1339 - 1348.] are discussed. (C) 2012 Elsevier Ltd. All rights re ...
Blast-furnace slags are widely used as supplementary cementitious materials in blended cements because of their relatively high reactivity. This study describes the effect of substituting Ca by Mg on the reactivity of synthetic glass with similar compositi ...
The filler effect, due to the physical presence of mineral additions in cement, is mainly known to accelerate the hydration of the clinker component. Previously, this was attributed to the surface of the filler providing nucleation sites for C-S-H as there ...
Tricalcium aluminate (C3A) is one of the main constituents of Portland cement. Even though it represents less than 10% of the total composition, its strong reaction with water can lead to a rapid setting, called flash set. Gypsum is added to regulate this ...
