Mapping of Functional Groups in Metal-Organic Frameworks
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Particle size distribution (PSD) is a relevant property of powdered solid matter since it directly influences the functionality of solid products such as pharmaceutics, cosmetics, abrasives, ceramics, metals, pigments, catalysts, and chemical reactants. Se ...
Covalent organic frameworks (COFs) are a class of advanced nanoporous polymeric materials which combine the crystallinity of metalorganic frameworks (MOFs) with the stability and potentially low-cost organic chemistry of porous polymer networks (PPNs). Lik ...
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Cerium(III) and cerium(IV) both form formate complexes. However, the species in aqueous solution and the solid-state structures are surprisingly different. Ce(III) shows only mononuclear complexes in aqueous solution, whereas Ce(IV) forms a stable hexanucl ...
Metal-organic frameworks with high stability have been pursued for many years due to the sustainability requirement for practical applications. However, researchers have had great difficulty synthesizing chemically ultra-stable, highly porous metal-organic ...
During the formation of metal–organic frameworks (MOFs), metal centres can coordinate with the intended organic linkers, but also with solvent molecules. In this case, subsequent activation by removal of the solvent molecules creates unsaturated ‘open’ met ...
Several nitrosyl complexes of Fe and Co have been prepared using the sterically hindered Ar-nacnac ligand (Ar-nacnac = anion of [(2,6- diisopropylphenyl)NC(Me)]2CH). The dinitrosyliron complexes [Fe(NO)2(Ar-nacnac)] (1) and (Bu4N)[Fe(NO) 2(Ar-nacnac)] (2) ...
Due to the current interest in nanotechnology, there is a strong desire for comprehensive knowledge on the underlying mechanisms governing the nanometric machining process. This article employs molecular dynamics to study nanomachining in ductile crystalli ...
In light of the already proven applications of transition-metal (TM) oxide clusters, including catalysis, selective sorption, sepns., mol. recognition, environmental decontamination, and nanotechnol., one can imagine that the development of framework mater ...
Polaritons are an odd cross-breed of a particle, half-matter, half-light. They could offer an abundant crop of new and improved optoelectronic devices — a promise already being fulfilled. ...