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Base-Free Non-Noble-Metal-Catalyzed Hydrogen Generation from Formic Acid: Scope and Mechanistic Insights

Related publications (46)

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Frustrated Lewis pairs (FLPs), featuring reactive combinations of Lewis acids and Lewis bases, have been utilized for myriad metal-free homogeneous catalytic processes. Immobilizing the active Lewis sites to a solid support, especially to porous scaffolds, ...

Amer Chemical Soc2024

Photogeneration of Hydrogen: Insights from a Pt(II)-Complex Incorporated into a Covalent Organic Framework

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Pt(II)-based molecular catalysts stand as a prototypical system in hydrogen evolution reactions (HER) owing to their consistently elevated activity levels. Their integration into heterogeneous systems thus provides an ideal platform to develop catalytic ma ...

Wiley-V C H Verlag Gmbh2024

Using Complex Hydrides for Hydrogen Storage and Direct Borohydride Fuel Cells for Electricity Production

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Hydrogen storage and utilization are the technologies to achieve carbon-neutral energy systems with renewable energy sources. Among the various materials that have been investigated, complex hydrides are a material exhibiting high gravimetric hydrogen dens ...

EPFL2023

Aging of industrial Fe-zeolite based catalysts for nitrous oxide abatement in nitric acid production plants

Davide Ferri, Pierdomenico Biasi, Filippo Buttignol

The influence of hydrothermal aging on the structural and catalytic properties of two commercial Fe-exchanged zeolite catalysts (Fe-FER and Fe-ZSM-5) in the extruded form employed for the removal of N2O from the exhaust of nitric acid production plants has ...

ROYAL SOC CHEMISTRY2022

Atomic Level Insights of Non-Noble Metal Catalysts for the Oxygen Evolution Reaction

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The conversion of intermittent renewable energy resources in the form of chemical bond, such as hydrogen production from electrochemical water splitting, is a promising way to satisfy the future global energy demand and address the environmental issues. Th ...

EPFL2021

Inorganic and Metal-Organic Heterogeneous Catalysts for Hydrogen Energy Applications

Fatma Pelin Uran

The main focus of this thesis is the exploration of inorganic and metal-organic heterogeneous catalysts for hydrogen (H2) energy applications. In particular, we investigated metal nanoparticles (NPs) and metal-organic frameworks (MOFs) for their employment ...

EPFL2021

Hydrogen production on demand by redox-mediated electrocatalysis: A kinetic study

Hubert Girault, Sunny Isaïe Maye, Danick Reynard

Producing hydrogen from water using a redox mediator on solid electrocatalyst particles in a reactor offers several advantages over classical electrolysis in terms of safety, membrane degradation, purity and flexibility. Herein, vanadium-mediated hydrogen ...

ELSEVIER SCIENCE SA2021

Atomic-Step Enriched Ruthenium-Iridium Nanocrystals Anchored Homogeneously on MOF-Derived Support for Efficient and Stable Oxygen Evolution in Acidic and Neutral Media

Vasiliki Tileli, Bo Li, Junjie Li, Lei Liu, Yue Li

Achieving an efficient and stable oxygen evolution reaction (OER) in an acidic or neutral medium is of paramount importance for hydrogen production via proton exchange membrane water electrolysis (PEM-WE). Supported iridium-based nanoparticles (NPs) are th ...

AMER CHEMICAL SOC2021

Micro-Electrode with Fast Mass Transport for Enhancing Selectivity of Carbonaceous Products in Electrochemical CO2 Reduction

Mingkui Wang, Jingshan Luo, Dan Ren, Xiaoyu Zhang, Qixing Zhang

During electrochemical carbon dioxide (CO2) reduction on copper electrodes in an aqueous electrolyte, one of the key challenges is the competition between hydrogen evolution and CO2 reduction, especially under large current density. Here, micro-electrodes ...

WILEY-V C H VERLAG GMBH2021

Recent progress in syngas production via catalytic CO2 hydrogenation reaction

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Synthesis gas production through the catalytic reverse water-gas shift (RWGS) reaction is an attractive option for the conversion of CO2 to fuels. Many metal-based catalysts have been introduced for this reaction in order to provide high activity, CO selec ...

ELSEVIER2021

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