CrystallographyCrystallography is the experimental science of determining the arrangement of atoms in crystalline solids. Crystallography is a fundamental subject in the fields of materials science and solid-state physics (condensed matter physics). The word crystallography is derived from the Ancient Greek word κρύσταλλος (; "clear ice, rock-crystal"), with its meaning extending to all solids with some degree of transparency, and γράφειν (; "to write").
Stacking (chemistry)In chemistry, pi stacking (also called π–π stacking) refers to the presumptive attractive, noncovalent pi interactions (orbital overlap) between the pi bonds of aromatic rings. However this is a misleading description of the phenomena since direct stacking of aromatic rings (the "sandwich interaction") is electrostatically repulsive.
Geiger counterA Geiger counter (also known as a Geiger–Müller counter or G-M counter) is an electronic instrument used for detecting and measuring ionizing radiation. It is widely used in applications such as radiation dosimetry, radiological protection, experimental physics and the nuclear industry. It detects ionizing radiation such as alpha particles, beta particles, and gamma rays using the ionization effect produced in a Geiger–Müller tube, which gives its name to the instrument.
PolysulfidePolysulfides are a class of chemical compounds derived from anionic chains of sulfur atoms. There are two main classes of polysulfides: inorganic and organic. The inorganic polysulfides have the general formula Sn2−. These anions are the conjugate bases of polysulfanes . Organic polysulfides generally have the formulae , where R = alkyl or aryl. The alkali metal polysulfides arise by treatment of a solution of sulfide, e.g. sodium sulfide, with elemental sulfur: S2- + n S → Sn+12− In some cases, these anions have been obtained as organic salts, which are soluble in organic solvents.
Chain terminationChain termination is any chemical reaction that ceases the formation of reactive intermediates in a chain propagation step in the course of a polymerization, effectively bringing it to a halt. In polymer chemistry, there are several mechanisms by which a polymerization reaction can terminate depending on the mechanism and circumstances of the reaction. A method of termination that applies to all polymer reactions is the depletion of monomer. In chain growth polymerization, two growing chains can collide head to head causing the growth of both of the chains to stop.
Proportional counterThe proportional counter is a type of gaseous ionization detector device used to measure particles of ionizing radiation. The key feature is its ability to measure the energy of incident radiation, by producing a detector output pulse that is proportional to the radiation energy absorbed by the detector due to an ionizing event; hence the detector's name. It is widely used where energy levels of incident radiation must be known, such as in the discrimination between alpha and beta particles, or accurate measurement of X-ray radiation dose.