Comprehensive study of carbon dioxide adsorption in the metal-organic frameworks M-2(dobdc) (M = Mg, Mn, Fe, Co, Ni, Cu, Zn)
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Three-dimensionally hierarchical flowerlike MgO hollow spheres with an extremely high surface area of 343 m(2) g(-1) were prepared through a facile and environmentally friendly solvothermal route. The maximum adsorption capacity at natural pH reached 569.7 ...
Royal Soc Chemistry2016
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Molecular simulations and NMR relaxometry experiments demonstrate that pure benzene or xylene confined in isoreticular metal-organic frameworks (IRMOFs) exhibit true vapor-liquid phase equilibria where the effective critical point may be reduced by tuning ...
Wiley-Blackwell2015
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Owing to their high surface areas, tunable pore dimensions, and adjustable surface functionality, metal-org. frameworks (MOFs) can offer advantages for a variety of gas storage and gas sepn. applications. In an effort to help curb greenhouse gas emissions ...
The crystallographic characterization of framework-guest interactions in metal-organic frameworks allows the location of guest binding sites and provides meaningful information on the nature of these interactions, enabling the correlation of structure with ...
For applications of metal-organic frameworks (MOFs) such as gas storage and separation, flexibility is often seen as a parameter that can tune material performance. In this work we aim to determine the optimal flexibility for the shape selective separation ...
American Chemical Society2017
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Boron doped graphene oxide (B-GO) is a highly effective adsorbent for ammonia due to the high density of strong Lewis acid sites arising from the boron. GO was doped by various amounts of boron described as xB-GO (x= 1.0, 3.0, and 5.0). B-GO was successful ...
Wiley-V C H Verlag Gmbh2017
Results are presented that explore the dynamic structural changes occurring in two highly flexible nanocryst. metal-org. framework (MOF) compds. during the adsorption and desorption of pure gases and binary mixts. The Ni(1,2-bis(4-pyridyl)ethylene)[Ni(CN)4 ...
2015
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Metal-organic frameworks (MOFs) are versatile nanoporous materials that have gained significant interest as low heat capacity, high selectivity sorbents for CO2 capture applications. Large-scale atomistic simulations for identifying high-performance MOFs a ...
Amer Chemical Soc2015
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Some nanoporous, crystalline materials possess dynamic constituents, for example, rotatable moieties. These moieties can undergo a conformation change in response to the adsorption of guest molecules, which qualitatively impacts adsorption behavior. We pos ...
National Academy of Sciences2017
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Metal org. frameworks (MOFs) are cryst. materials that contain metal-ions or metal-ion clusters as nodes and org. ligands as linkers to form 1-, 2-, and 3-D structures. In addn. to their convenient modular synthesis and chem. tunability, this class of mate ...
