Electron paramagnetic resonanceElectron paramagnetic resonance (EPR) or electron spin resonance (ESR) spectroscopy is a method for studying materials that have unpaired electrons. The basic concepts of EPR are analogous to those of nuclear magnetic resonance (NMR), but the spins excited are those of the electrons instead of the atomic nuclei. EPR spectroscopy is particularly useful for studying metal complexes and organic radicals. EPR was first observed in Kazan State University by Soviet physicist Yevgeny Zavoisky in 1944, and was developed independently at the same time by Brebis Bleaney at the University of Oxford.
Finite differenceA finite difference is a mathematical expression of the form f (x + b) − f (x + a). If a finite difference is divided by b − a, one gets a difference quotient. The approximation of derivatives by finite differences plays a central role in finite difference methods for the numerical solution of differential equations, especially boundary value problems. The difference operator, commonly denoted is the operator that maps a function f to the function defined by A difference equation is a functional equation that involves the finite difference operator in the same way as a differential equation involves derivatives.
Pointed spaceIn mathematics, a pointed space or based space is a topological space with a distinguished point, the basepoint. The distinguished point is just simply one particular point, picked out from the space, and given a name, such as that remains unchanged during subsequent discussion, and is kept track of during all operations. Maps of pointed spaces (based maps) are continuous maps preserving basepoints, i.e.
Interaction pictureIn quantum mechanics, the interaction picture (also known as the interaction representation or Dirac picture after Paul Dirac) is an intermediate representation between the Schrödinger picture and the Heisenberg picture. Whereas in the other two pictures either the state vector or the operators carry time dependence, in the interaction picture both carry part of the time dependence of observables. The interaction picture is useful in dealing with changes to the wave functions and observables due to interactions.
Difference quotientIn single-variable calculus, the difference quotient is usually the name for the expression which when taken to the limit as h approaches 0 gives the derivative of the function f. The name of the expression stems from the fact that it is the quotient of the difference of values of the function by the difference of the corresponding values of its argument (the latter is (x + h) - x = h in this case). The difference quotient is a measure of the average rate of change of the function over an interval (in this case, an interval of length h).
Loop spaceIn topology, a branch of mathematics, the loop space ΩX of a pointed topological space X is the space of (based) loops in X, i.e. continuous pointed maps from the pointed circle S1 to X, equipped with the compact-open topology. Two loops can be multiplied by concatenation. With this operation, the loop space is an A∞-space. That is, the multiplication is homotopy-coherently associative. The set of path components of ΩX, i.e. the set of based-homotopy equivalence classes of based loops in X, is a group, the fundamental group π1(X).
American and British English spelling differencesDespite the various English dialects spoken from country to country and within different regions of the same country, there are only slight regional variations in English orthography, the two most notable variations being British and American spelling. Many of the differences between American and British English / Commonwealth English date back to a time before spelling standards were developed. For instance, some spellings seen as "American" today were once commonly used in Britain, and some spellings seen as "British" were once commonly used in the United States.
Suspension (topology)In topology, a branch of mathematics, the suspension of a topological space X is intuitively obtained by stretching X into a cylinder and then collapsing both end faces to points. One views X as "suspended" between these end points. The suspension of X is denoted by SX or susp(X). There is a variation of the suspension for pointed space, which is called the reduced suspension and denoted by ΣX. The "usual" suspension SX is sometimes called the unreduced suspension, unbased suspension, or free suspension of X, to distinguish it from ΣX.