A scaling factor theorem for homonuclear dipolar decoupling in solid-state NMR spectroscopy
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A method for nuclear magnetic resonance (NMR) spectroscopy of a sample comprises preparation of the sample and carrying out an NMR spectroscopy measurement. Preparation includes excitation of long lived coherences (LLC) between the singlet state S0 and the ...
A Method for nuclear magnetic resonance (NMR) spectroscopy of a sample comprising the following steps: (a) excitation of long lived coherences (LLC) between the singlet state So and the central triplet state To of nuclei of the sample by initiating irradia ...
In numerous biological processes that constitute the base of living organisms, protein function is fundamentally related to internal dynamics occurring on μs-ms time scales that can give rise to chemical exchange contributions to relaxation. In a heteronuc ...
A drastic reduction of the time required for two-dimensional NMR experiments can be achieved by reducing or skipping the recovery delay between successive experiments. Novel SMAll Recovery Times (SMART) methods use orthogonal pulsed field gradients in thre ...
Slow dynamic processes, such as biomolecular folding/unfolding, macromolecular diffusion, etc., can be conveniently monitored by solution-state two-dimensional (2D) NMR spectroscopy, provided the inverse of their rate constants does not exceed the nuclear ...
Developments towards an understanding of the nature of conductance at the interface between two different metallic layers – ferromagnetic and non magnetic – as well as the discovery of giant magnetoresistance have stirred attention from both the scientific ...
The magnetic properties of the two uranium coordination compounds, [K(18c6)][U(OSi-((OBu)-Bu-t)(3))(4)] and [K(18c6)][U(N(SiMe3)(2))(4)], both presenting the U-III ion in similar pseudotetrahedral coordination environments but with different O- or N-donor ...
The magnetic shielding tensors of protons of water in barium chlorate monohydrate are investigated at room temperature by means of solid-state NMR spectroscopy, both for static powders and under magic-angle spinning conditions, using one- and two-dimension ...
Relaxation processes induced by the antisymmetric part of the chemical shift anisotropy tensor (henceforth called anti-CSA) are usually neglected in NMR relaxation studies. It is shown here that anti-CSA components contribute to longitudinal relaxation rat ...
The inherent distortions in echo-planar imaging that arise due to inhomogeneities in the static magnetic field can lead to difficulties when attempting to obtain structurally accurate diffusion-tensor imaging data. Parallel acceleration techniques can redu ...