Resonator with reduced sample heating and increased homogeneity for solid-state NMR
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Sensitivity in Nuclear Magnetic Resonance (NMR), especially in solid-state NMR, has always been a challenging and important issue and thus a motivation for new developments. The magnetic field B0, the gyromagnetic ratios of the observed nuclei, as well as ...
We introduce a new approach to improve structural and dynamical determination of large metalloproteins using solid-state nuclear magnetic resonance (NMR) with H-1 detection under ultrafast magic angle spinning (MAS). The approach is based on the rapid and ...
A synthetic procedure for the synthesis of two molecular borophosphate cages is described. Heating of ethyl phosphate with phenylboronic or 4-formylboronic acid in toluene gives [6+6] condensation products of the general formula EtOPO3BAr. Crystallogr ...
Protein structure determination by proton-detected magic-angle spinning (MAS) NMR has focused on highly deuterated samples, in which only a small number of protons are introduced and observation of signals from side chains is extremely limited. Here, we sh ...
Pseudocontact shifts (PCSs) arise in para-magnetic systems in which the susceptibility tensor is anisotropic. PCSs depend upon the distance from the paramagnetic center and the position relative to the susceptibility tensor, and they can be used as structu ...
Radio frequency (RF) heating experiments have recently been conducted in JET (He-3)-H plasmas. This type of plasmas will be used in ITER's non-activated operation phase. Whereas a companion paper in this same PPCF issue will discuss the RF heating scenario ...
Nuclear magnetic resonance (NMR) is a non-invasive tool for the study of human diseases. In particular, carbon-13 magnetic resonance spectroscopy (13C MRS) is a promising derivative tool for investigating metabolism in vivo, as it allows the non-invasive m ...
Terahertz radiation, THz = 1012 Hz, refers to electromagnetic signals with frequencies in the range of 0.3 to 3 THz, and wavelengths between 1 and 0.1 mm. This part of the electromagnetic spectrum is located in between millimeter waves at lower frequencies ...
Techniques based on spin resonance effects are amongst the most powerful analytical methods in both modern chemistry and medicine. Recent years have seen a trend toward scaled-down detection coils, exploiting the fact that a reduction of the detector size ...
Earthing of electrical installations is mainly governed by safety rules. Electromagnetic compatibility also deals with earthing, among other circuit characteristics. Tokamaks are large-scale electrical installations that are known to generate large and low ...