Solid-state nuclear magnetic resonanceSolid-state NMR (ssNMR) spectroscopy is a technique for characterizing atomic level structure in solid materials e.g. powders, single crystals and amorphous samples and tissues using nuclear magnetic resonance (NMR) spectroscopy. The anisotropic part of many spin interactions are present in solid-state NMR, unlike in solution-state NMR where rapid tumbling motion averages out many of the spin interactions.
Spin (physics)Spin is an intrinsic form of angular momentum carried by elementary particles, and thus by composite particles such as hadrons, atomic nuclei, and atoms. Spin should not be understood as in the "rotating internal mass" sense: spin is a quantized wave property. The existence of electron spin angular momentum is inferred from experiments, such as the Stern–Gerlach experiment, in which silver atoms were observed to possess two possible discrete angular momenta despite having no orbital angular momentum.
SpinorIn geometry and physics, spinors spɪnɚ are elements of a complex number-based vector space that can be associated with Euclidean space. A spinor transforms linearly when the Euclidean space is subjected to a slight (infinitesimal) rotation, but unlike geometric vectors and tensors, a spinor transforms to its negative when the space rotates through 360° (see picture). It takes a rotation of 720° for a spinor to go back to its original state.
Spin groupIn mathematics the spin group Spin(n) is a Lie group whose underlying manifold is the double cover of the special orthogonal group SO(n) = SO(n, R), such that there exists a short exact sequence of Lie groups (when n ≠ 2) The group multiplication law on the double cover is given by lifting the multiplication on . As a Lie group, Spin(n) therefore shares its dimension, n(n − 1)/2, and its Lie algebra with the special orthogonal group. For n > 2, Spin(n) is simply connected and so coincides with the universal cover of SO(n).
Angular momentum couplingIn quantum mechanics, the procedure of constructing eigenstates of total angular momentum out of eigenstates of separate angular momenta is called angular momentum coupling. For instance, the orbit and spin of a single particle can interact through spin–orbit interaction, in which case the complete physical picture must include spin–orbit coupling. Or two charged particles, each with a well-defined angular momentum, may interact by Coulomb forces, in which case coupling of the two one-particle angular momenta to a total angular momentum is a useful step in the solution of the two-particle Schrödinger equation.
Spin–orbit interactionIn quantum physics, the spin–orbit interaction (also called spin–orbit effect or spin–orbit coupling) is a relativistic interaction of a particle's spin with its motion inside a potential. A key example of this phenomenon is the spin–orbit interaction leading to shifts in an electron's atomic energy levels, due to electromagnetic interaction between the electron's magnetic dipole, its orbital motion, and the electrostatic field of the positively charged nucleus.
Nuclear magnetic resonanceNuclear magnetic resonance (NMR) is a physical phenomenon in which nuclei in a strong constant magnetic field are perturbed by a weak oscillating magnetic field (in the near field) and respond by producing an electromagnetic signal with a frequency characteristic of the magnetic field at the nucleus. This process occurs near resonance, when the oscillation frequency matches the intrinsic frequency of the nuclei, which depends on the strength of the static magnetic field, the chemical environment, and the magnetic properties of the isotope involved; in practical applications with static magnetic fields up to ca.
Nuclear magnetic resonance spectroscopyNuclear magnetic resonance spectroscopy, most commonly known as NMR spectroscopy or magnetic resonance spectroscopy (MRS), is a spectroscopic technique to observe local magnetic fields around atomic nuclei. This spectroscopy is based on the measurement of absorption of electromagnetic radiations in the radio frequency region from roughly 4 to 900 MHz. Absorption of radio waves in the presence of magnetic field is accompanied by a special type of nuclear transition, and for this reason, such type of spectroscopy is known as Nuclear Magnetic Resonance Spectroscopy.
Spin representationIn mathematics, the spin representations are particular projective representations of the orthogonal or special orthogonal groups in arbitrary dimension and signature (i.e., including indefinite orthogonal groups). More precisely, they are two equivalent representations of the spin groups, which are double covers of the special orthogonal groups. They are usually studied over the real or complex numbers, but they can be defined over other fields. Elements of a spin representation are called spinors.
Spin-1/2In quantum mechanics, spin is an intrinsic property of all elementary particles. All known fermions, the particles that constitute ordinary matter, have a spin of 1/2. The spin number describes how many symmetrical facets a particle has in one full rotation; a spin of 1/2 means that the particle must be rotated by two full turns (through 720°) before it has the same configuration as when it started. Particles having net spin 1/2 include the proton, neutron, electron, neutrino, and quarks.
