Charge sepn. in sintered colloidal TiO2 film electrodes was studied by action spectra in SCN-/(SCN)2- the UV region. Electrodes with different film thicknesses were studied. Current generation is most efficient close to the back contact. Monochromatic quantum efficiency of ≤77% and optimum overall quantum efficiency were attained at a colloidal film thickness of ∼4 μm. Illumination through the back side contact gives a theor. quantum efficiency of 100% to a depth of 0.5 μm from the back contact. The origin of the unexpectedly high current generation in the colloidal films was studied.
Kevin Sivula, Jun Ho Yum, Rebekah Anne Wells, Liang Yao, Nestor Guijarro Carratala, Yongpeng Liu, Florent Alexandre Boudoire, Arvindh Sekar, Han-Hee Cho
Raffaella Buonsanti, Aurélien Bornet, Anna Loiudice, Ona Segura Lecina