Structural destabilization induced by lithium intercalation in MoS2 and related compounds
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Metal organic frameworks (MOFs) are extended structures composed of a network of organic ligands and metal ions or clusters connected to each other via coordination bonds. The numerous choices of organic ligands and metal coordination geometries have led t ...
Hqpzc has been synthesized by a highly efficient procedure using the ionic liquid TBAB as an environmentally benign reaction medium. [Cu(qpzc)(OAc)]H2O (1) and [Zn(qpzc)(OAc)(H2O)] (2), complexes of the deprotonated ligand, qpzc [qpzc ...
Because of their remarkable and unmatched optical and magnetic properties, the lanthanides are under the limelight when it comes to high technology. These elements are used in strategic applications such as optical glasses and lasers, telecommunications, l ...
Described are the synthesis and characterization of two, potentially tetradentate, N2S2 Schiff-base ligands, containing a disulfide bond, N,N'-bis(3-phenylprop-2-en-l-ylidene)-2,2'-disulfanediyldianiline (L-1) and N,N'-bis(3,3-diphenylprop-2-en-1-ylidene)- ...
We present the results of temperature-dependent self-assembly of dicarbonitrile-pentaphenyl molecules (NC-Ph-5-CN) on Cu(111). Our low-temperature scanning tunneling microscopy study reveals the formation of metal-organic and purely organic structures, dep ...
The title compound, (UO2)2Cl2(OH)2(H2O)4, was obtained unintentionally as the product of an attempted reaction between uranium(VI) oxide dihydrate, UO3⋅2H2O, and hydrogen bis(trifluoromethylsulfonyl)imide (HTf2N), in an experiment to obtain ...
We study nonlocal effects associated with particle collisions in dense suspension flows, in the context of the Affine Solvent Model, known to capture various aspects of the jamming transition. We show that an individual collision changes significantly the ...
We investigate the zero-temperature behavior of the classical Heisenberg model on the triangular lattice in which the competition between exchange interactions of different orders favors a relative angle between neighboring spins Phi is an element of (0,2 ...
The geometric and electronic structure of two structurally similar metal organic networks grown on the Au(111) surface is investigated by scanning tunnelling microscopy (STM) and spectroscopy (STS) combined with density functional theory (DFT) calculations ...
The incommensurately modulated structure of the mineral natrite has been refined for the first time. Two single-crystal grains, Lv and Kh, from two different occurrences [Mt. Karnasurt, Lovozero massif (Lv), Kola peninsula, Russia, and the pegmatite of Mt. ...