Stress reduction mechanisms during photopolymerization of functionally graded polymer nanocomposite coatings
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The behaviour of brittle matrix fibre reinforced-composites is dependent of the properties of its constituents (fibre, matrix and fibre-matrix interface) and is affected by the mechanical and environmental loads. The fracture of a unidirectional composite ...
This thesis is devoted to the study of the dispersion polymerization of methyl methacrylate in supercritical carbon dioxide (scCO2), using a poly(dimethylsiloxane) macromonomer (PDMS macromonomer) as stabilizer. Supercritical fluids (SCF) and SCF mixtures ...
The purpose of this thesis is to characterize internal strains in polymeric materials due to consolidation. In view of this, optical Fiber Bragg Grating sensors are an excellent non-destructive tool for internal strain characterization and damage detection ...
As the range of applications for fiber-reinforced polymer (FRP) composite materials in civil engineering constantly increases, there is more and more concern with regard to their performance in critical environments. The fire behavior of composite material ...
SU8-carbon nanotube composites have been produced to enhance the mechanical, electrical, and thermal properties of SU8 photoresists. Homogeneous composites materials have been obtained when multiwalled carbon nanotubes (MWCNTs) functionalized with COOH gro ...
The organic polymers incorporating inorganic nanoparticles can result in material possessing with unique size-dependent properties, such as mechanical, optical, electrical, thermal and magnetic, that can be istinctively conveyed into the composite by the s ...
Three methods to mix ceramic fillers, hydroxyapatite or β-tricalcium phosphate, with a polymer matrix, a poly l-lactic acid, are investigated as a first step prior to supercritical foaming to prepare porous composite structures for biomedical applications. ...
The aim of this thesis was to investigate the process-structure-property relationships of UV-curable hyperbranched polymer (HBP)/silica nanocomposites. Special attention was paid to the interplay between photo-conversion, rheological behavior, shrinkage, a ...
Ferroelectric ceramic – polymer composites have a unique mix of electrical and mechanical properties. Piezoelectric and pyroelectric activity, a wide range of dielectric constants and high breakdown strength are combined with mechanical flexibility, formab ...
The objective of this study was to investigate the behavior of highly functional acrylates, during isothermal ultraviolet (UV) curing. The materials included a pentafunctional acrylate and two acrylated hyperbranched polymers, one with a stiff polyester co ...