Publication

Silaffins in Silica Biomineralization and Biomimetic Silica Precipitation

Related publications (32)

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Inorganic nanoparticles (NPs) have emerged as promising tools in biomedical applications, owing to their inherent physicochemical properties and their ease of functionalization. In all potential applications, the surface functionalization strategy is a key ...

2023

Permeability, alteration, and microstructure: A (hopefully) coupled rock physics and geochemical approach to how rock-fluid interactions change permeability

Alexandra Roma Larisa Kushnir

Permeability is a key physical property across all spatial scales in the Earth’s crust and exerts significant control on the behaviour of Earth systems, with implications for natural hazards (e.g., earthquakes, slope instabilities, volcanic eruptions) and ...

2023

Materials with thermal-invariant elastic properties are of interest for resonant device frequency and dimensional stability of precision devices. Here, we demonstrate that the temperature coefficient of elasticity (TCE) of amorphous silica can be locally r ...

2022

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The dissolution kinetics of silica-containing minerals in aggregates influences strongly the process of ASR in concrete. In this paper, the effect of different ions on the dissolution rates of SiO2 (amorphous and quartz) and feldspars at high pH values was ...

PERGAMON-ELSEVIER SCIENCE LTD2022

Calcium silicate hydrate (C-S-H) is the main hydration product in Portland and blended cements, and greatly affects durability and mechanical properties of the hydrated cement. In the presence of Al-rich supplementary cementitious materials (SCMs), C-(A-)S ...

EPFL2022

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Water free, non-oxidative catalytic dehydrogenation of methanol to formaldehyde is an important process for the formation of anhydrous, molecular formaldehyde (FA). Sodium or sodium-containing salts were shown to catalyze the reaction, but their reaction m ...

2021

For several decades, food-grade synthetic amorphous silica (SAS) have been used as a technological additive to reduce caking of food powders. Human exposure is thus inevitable and safety concerns are taken seriously. The toxicity of silica in general and S ...

PERGAMON-ELSEVIER SCIENCE LTD2020

Structural description of surfaces and interfaces in biominerals by DNP SENS

David Lyndon Emsley, David Benjamin Roger Antoine Gajan

Biological mineralized tissues are hybrid materials with complex hierarchical architecture composed of biominerals often embedded in an organic matrix. The atomic-scale comprehension of surfaces and organo-mineral interfaces of these biominerals is of para ...

ACADEMIC PRESS INC ELSEVIER SCIENCE2019

Atomic Description of the Interface between Silica and Alumina in Aluminosilicates through Dynamic Nuclear Polarization Surface-Enhanced NMR Spectroscopy and First-Principles Calculations

David Lyndon Emsley, Aaron James Rossini

Despite the widespread use of amorphous aluminosilicates (ASA) in various industrial catalysts, the nature of the interface between silica and alumina and the atomic structure of the catalytically active sites are still subject to debate. Here, by the use ...

American Chemical Society2015

Silica-surface reorganization during organotin grafting evidenced by Sn-119 DNP SENS: a tandem reaction of gem-silanols and strained siloxane bridges

David Lyndon Emsley, Aaron James Rossini

Grafting reactive molecular complexes on dehydroxylated amorphous silica is a strategy to develop ``single-site'' heterogeneous catalysts. In general, only the reactivity of isolated silanols is invoked for silica dehydroxylated at 700 degrees C ([SiO2-700 ...

2014

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