X-ray irradiation synthesis of PEG-coated Au-Pd nanoparticles
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Monodispersed Pd nanoparticles of 5 and 10 nm were obtained via reduction of Pd(acac)2 dissolved in ionic liquid (IL), [bmim][PF6], or [bmimOH][TF2N], supported on carbon nanofibers (CNF) anchored to sintered metal fibers (SMF). Using [bmimOH][TF2N], the m ...
Pd nanoparticles (2 nm) stabilized in the micelle core of poly(ethylene oxide)-block-poly(2-vinylpyridine) were studied in partial hydrogenation of 2-butyne-1,4-diol. Both unsupported micelles (0.6 kg Pd/m3) and supported ones on g-Al2O3 (0.042% Pd) showed ...
The relation between the catalyst potential and the catalytic performance has been investigated in the gas-phase combustion of propylene with oxygen over rhodium catalysts at 375 DegC. The rhodium catalyst, deposited on yttria-stabilized zirconia (YSZ) sol ...
The relation between the catalyst potential and the catalytic performance has been investigated in the gas-phase combustion of propylene with oxygen over rhodium catalysts at 375 DegC. The rhodium catalyst, deposited on yttria-stabilized zirconia (YSZ) sol ...
The use of formate-based ammonia precursors as alternatives to urea in the selective catalytic reduction (SCR) process requires that formic acid released upon their thermolysis in the hot exhaust is rapidly decomposed to carbon dioxide. This work aims at t ...
Novel efficient structured combustion catalysts based on sintered metal fiber filters (MFF) were developed. To increase sp. surface area (SSA), metal fibers were coated by crack-free porous oxide films of SiO2, Al2O3, porous glass, and mesoporous SBA-15 si ...