NO binding kinetics in myoglobin investigated by picosecond Fe K-edge absorption spectroscopy
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The research proposal describes the spectroscopic technique to study the intermediate state of protonated peptides formed after the UV excitation. It was shown previously that with the assistance of the CO2 laser the side chain loss fragmentation was enhan ...
Ultrafast X-ray absorption spectroscopy is a powerful tool to observe electronic and geometric structures of short-lived reaction intermediates. The ab initio FEFF9 code is applied to simulate the Pt L-3-edge XANES spectrum of the photocatalytic diplatinum ...
Time-resolved x-ray absorption fine structure (XAFS) spectroscopy with picosecond temporal resolution is a new method to observe electronic and geometric structures of short-lived reaction intermediates. It combines an intense femtosecond laser source sync ...
Spie-Int Soc Optical Engineering, Po Box 10, Bellingham, Wa 98227-0010 Usa2007
Identifying the intermediate species along a reaction pathway is a first step towards a complete understanding of the reaction mechanism, but often this task is not trivial. There has been a strong on-going debate: which of the three intermediates, the CHI ...
In this thesis we followed the synergetic approach of combining ultrafast optical and X-ray spectroscopies to unravel the electronic and geometric structural dynamics of the solvated binuclear transition metal complex [Pt2(P2O5H2)4] 4- (PtPOP). This molecu ...
Time-resolved x-ray absorption fine structure (XAFS) spectroscopy with picosecond temporal resoln. is a new method to observe electronic and geometric structures of short-lived reaction intermediates. It combines an intense femtosecond laser source synchro ...
