Core formation and core composition from coupled geochemical and geophysical constraints

The formation of Earth's core left behind geophysical and geochemical signatures in both the core and mantle that remain to this day. Seismology requires that the core be lighter than pure iron and therefore must contain light elements, and the geochemistry of mantle-derived rocks reveals extensive siderophile element depletion and fractionation. Both features are inherited from metal-silicate differentiation in primitive Earth and depend upon the nature of physio-chemical conditions that prevailed during core formation. To date, core formation models have only attempted to address the evolution of core and mantle compositional signatures separately, rather than seeking a joint solution. Here we combine experimental petrology, geochemistry, mineral physics and seismology to constrain a range of core formation conditions that satisfy both constraints. We find that core formation occurred in a hot (liquidus) yet moderately deep magma ocean not exceeding 1,800 km depth, under redox conditions more oxidized than present-day Earth. This new scenario, at odds with the current belief that core formation occurred under reducing conditions, proposes that Earth's magma ocean started oxidized and has become reduced through time, by oxygen incorporation into the core. This core formation model produces a core that contains 2.7-5% oxygen along with 2-3.6% silicon, with densities and velocities in accord with radial seismic models, and leaves behind a silicate mantle that matches the observed mantle abundances of nickel, cobalt, chromium, and vanadium.

A seismologically consistent compositional model of Earth's core

James Badro

Earth's core is less dense than iron, and therefore it must contain "light elements," such as S, Si, O, or C. We use ab initio molecular dynamics to calculate the density and bulk sound velocity in liquid metal alloys at the pressure and temperature conditions of Earth's outer core. We compare the velocity and density for any composition in the (Fe-Ni, C, O, Si, S) system to radial seismological models and find a range of compositional models that fit the seismological data. We find no oxygen-free composition that fits the seismological data, and therefore our results indicate that oxygen is always required in the outer core. An oxygen-rich core is a strong indication of high-pressure and high-temperature conditions of core differentiation in a deep magma ocean with an FeO concentration (oxygen fugacity) higher than that of the present-day mantle.

Natl Acad Sciences2014

Terrestrial Accretion Under Oxidizing Conditions

James Badro

The abundance of siderophile elements in the mantle preserves the signature of core formation. On the basis of partitioning experiments at high pressure (35 to 74 gigapascals) and high temperature (3100 to 4400 kelvin), we demonstrate that depletions of slightly siderophile elements (vanadium and chromium), as well as moderately siderophile elements (nickel and cobalt), can be produced by core formation under more oxidizing conditions than previously proposed. Enhanced solubility of oxygen in the metal perturbs the metal-silicate partitioning of vanadium and chromium, precluding extrapolation of previous results. We propose that Earth accreted from materials as oxidized as ordinary or carbonaceous chondrites. Transfer of oxygen from the mantle to the core provides a mechanism to reduce the initial magma ocean redox state to that of the present-day mantle, reconciling the observed mantle vanadium and chromium concentrations with geophysical constraints on light elements in the core.

2013

Chemical Characterisation of Deep Earth Reservoirs

Hélène Marie Piet

Seismic imaging of the internal Earth has emphasized the inhomogeneity of its mantle. This interface layer of nearly 3000 km surrounding the central metallic core conducts heat released from the latter, which played a significant role in shaping the actual mantle as it currently is. The present state of the deep Earth (mainly the lower mantle and the core) is also a consequence of the physical properties of the material composing them. Large-low shear velocity provinces atop the core-mantle boundary, for example, are composed of a denser material than their surrounding environment but their origin, formation and survival over billions of years to mantle convection, is still largely debated. Here we use chemical partitioning to characterise the current composition of those deep Earth reservoirs and better understand the processes leading to their formation. In the first part, experiments were conducted in the laser-heated diamond anvil cell and the latest advances in microanalysis were used to refine iron partitioning between minerals of the lower mantle. We reconcile long-standing discrepancies in previous partitioning data and show that significant variations of silicate iron content are associated to changing ferric iron incorporation. We also note that such chemical variations might significantly affect the physical properties of the silicate, which might in turn provoke mantle rheology variations. Our results and observations thus provide a mineral physics based argument for the stabilization of deep Earth reservoirs and especially large structures like large low-shear-velocity provinces (LLSVPs). In the second and numerical part of the thesis, previous results on siderophile (iron-loving) element partitioning between metal and silicate were used to constrain some aspects of core formation. We constrain the chemical and physical state of the magma ocean during core formation explaining both the siderophile composition of the mantle and the light element composition of the core. We simulate the Moon-Forming Giant Impact in the last steps of Earth accretion, where we constrain the size of the impactor to be smaller than 15% of Earth's total mass, a roughly Mars-sized object, and further show that melting of the large fractions of the mantle upon impact by the giant impactor is consistent with siderophile composition of the bulk silicate Earth, which can have great implications for the geodynamical evolution of the mantle. In conclusions, given the fact that the mantle may have been almost fully molten, further crystallization may have isolated a layer of liquid primitive material at the base of the mantle possibly explaining the seismic signature of the LLSVPs associated with a strong thermochemical contrast with the surrounding mantle. The layered composition in iron of the actual mantle also provides a chemical argument for a viscously layered mantle, which could have helped sustain LLSVPs for billions of years from efficient convection.

EPFL2016

Chemical Characterisation of Deep Earth Reservoirs

Hélène Marie Piet

EPFL2016