Flame-Made WO3/CeOx-TiO2 Catalysts for Selective Catalytic Reduction of NOx by NH3
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Co-impregnation of vanadia and tungsta on titania produced highly active catalysts for the reduction of nitrogen oxides with ammonia but showed aging tendencies at temperatures around 600 °C. In order to preserve their low temperature activity after hydrot ...
Development of selective oxidation catalysts is a major concern of modern chemical industry. Among several systems, VTi-oxide based catalysts showed the most promising and versatile, able to catalyse key reactions like oxidation of o-xylene to phtalic anhy ...
We present cw and pulsed EPR experiments on V4+ in the rutile and anatase phases of TiO2. For the rutile phase, the cw data confirm earlier results, but the relaxation data are different from those previously reported. No earlier results for V4+ in the unr ...
Real-world vanadium-based catalysts for the selective catalytic reduction (SCR) of NO with NH3 are occasionally exposed to high temperatures, which can induce catalyst aging. In this work, a 2.0 wt% V2O5/WO3-TiO2 catalyst based on commercial WO3-TiO2 was l ...
The use of formate-based ammonia precursors as alternatives to urea in the selective catalytic reduction (SCR) process requires that formic acid released upon their thermolysis in the hot exhaust is rapidly decomposed to carbon dioxide. This work aims at t ...
Novel efficient structured combustion catalysts based on sintered metal fiber filters (MFF) were developed. To increase sp. surface area (SSA), metal fibers were coated by crack-free porous oxide films of SiO2, Al2O3, porous glass, and mesoporous SBA-15 si ...
The work presents the effect of K-doping on V/Ti-oxides taking into account: the surface acid–base properties and the structure of surface vanadia species in respect to the catalyst performance and deactivation. The structure of active surface species dete ...