Molecular self-assemblyIn chemistry and materials science, molecular self-assembly is the process by which molecules adopt a defined arrangement without guidance or management from an outside source. There are two types of self-assembly: intermolecular and intramolecular. Commonly, the term molecular self-assembly refers to the former, while the latter is more commonly called folding. Molecular self-assembly is a key concept in supramolecular chemistry. This is because assembly of molecules in such systems is directed through non-covalent interactions (e.
Self-assembly of nanoparticlesNanoparticles are classified as having at least one of three dimensions be in the range of 1-100 nm. The small size of nanoparticles allows them to have unique characteristics which may not be possible on the macro-scale. Self-assembly is the spontaneous organization of smaller subunits to form larger, well-organized patterns. For nanoparticles, this spontaneous assembly is a consequence of interactions between the particles aimed at achieving a thermodynamic equilibrium and reducing the system’s free energy.
MacrocycleMacrocycles are often described as molecules and ions containing a ring of twelve or more atoms. Classical examples include the crown ethers, calixarenes, porphyrins, and cyclodextrins. Macrocycles describe a large, mature area of chemistry. The formation of macrocycles by ring-closure is called macrocylization. Pioneering work was reported for studies on terpenoid macrocycles. The central challenge to macrocyclization is that ring-closing reactions do not favor the formation of large rings.
NanotechnologyNanotechnology, often shortened to nanotech, is the use of matter on atomic, molecular, and supramolecular scales for industrial purposes. The earliest, widespread description of nanotechnology referred to the particular technological goal of precisely manipulating atoms and molecules for fabrication of macroscale products, also now referred to as molecular nanotechnology. A more generalized description of nanotechnology was subsequently established by the National Nanotechnology Initiative, which defined nanotechnology as the manipulation of matter with at least one dimension sized from 1 to 100 nanometers (nm).
Flexibility methodIn structural engineering, the flexibility method, also called the method of consistent deformations, is the traditional method for computing member forces and displacements in structural systems. Its modern version formulated in terms of the members' flexibility matrices also has the name the matrix force method due to its use of member forces as the primary unknowns. Flexibility is the inverse of stiffness. For example, consider a spring that has Q and q as, respectively, its force and deformation: The spring stiffness relation is Q = k q where k is the spring stiffness.
PhthalocyaninePhthalocyanine () is a large, aromatic, macrocyclic, organic compound with the formula and is of theoretical or specialized interest in chemical dyes and photoelectricity. It is composed of four isoindole units linked by a ring of nitrogen atoms. = has a two-dimensional geometry and a ring system consisting of 18 π-electrons. The extensive delocalization of the π-electrons affords the molecule useful properties, lending itself to applications in dyes and pigments.
Delta baryonThe Delta baryons (or Δ baryons, also called Delta resonances) are a family of subatomic particle made of three up or down quarks (u or d quarks), the same constituent quarks that make up the more familiar protons and neutrons. Four closely related Δ baryons exist: _Delta++ (constituent quarks: uuu), _Delta+ (uud), _Delta0 (udd), and _Delta- (ddd), which respectively carry an electric charge of +2e, +1e, 0e, and -1e. The Δ baryons have a mass of about 1232MeV/c2; their third component of isospin and they are required to have an intrinsic spin of 3 /2 or higher (half-integer units).
Direct stiffness methodAs one of the methods of structural analysis, the direct stiffness method, also known as the matrix stiffness method, is particularly suited for computer-automated analysis of complex structures including the statically indeterminate type. It is a matrix method that makes use of the members' stiffness relations for computing member forces and displacements in structures. The direct stiffness method is the most common implementation of the finite element method (FEM).
IsospinIn nuclear physics and particle physics, isospin (I) is a quantum number related to the up- and down quark content of the particle. More specifically, isospin symmetry is a subset of the flavour symmetry seen more broadly in the interactions of baryons and mesons. The name of the concept contains the term spin because its quantum mechanical description is mathematically similar to that of angular momentum (in particular, in the way it couples; for example, a proton–neutron pair can be coupled either in a state of total isospin 1 or in one of 0).
Conjugated systemIn theoretical chemistry, a conjugated system is a system of connected p-orbitals with delocalized electrons in a molecule, which in general lowers the overall energy of the molecule and increases stability. It is conventionally represented as having alternating single and multiple bonds. Lone pairs, radicals or carbenium ions may be part of the system, which may be cyclic, acyclic, linear or mixed. The term "conjugated" was coined in 1899 by the German chemist Johannes Thiele.
