Carboxylic Acid Functionalized Clathrochelate Complexes: Large, Robust, and Easy-to-Access Metalloligands
Related publications (36)
Graph Chatbot
Chat with Graph Search
Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.
DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.
Here, the carboxamide ligandN-(thiazole-2-yl) picolinamide (L) was synthesized in an ionic liquid tetrabutylammonium bromide (TBAB) as the benign reaction medium. The sensitivity ofLtowards different metal-ions was investigated, and a comprehensive, logica ...
Metal-organic frameworks (MOFs) are coordination polymer materials in which inorganic metal ions or clusters are linked with multitopic organic ligands by means of coordination bonds. Their structural versatility allows for design of materials based on pre ...
Metal organic frameworks (MOFs) are extended structures composed of a network of organic ligands and metal ions or clusters connected to each other via coordination bonds. The numerous choices of organic ligands and metal coordination geometries have led t ...
Elsevier2017
, ,
The electrochemical reduction of CO2 to ethylene provides a carbon-neutral avenue for the conversion of CO2 to value-added fuels and feedstocks, so contributing to the storage of intermittent renewable electricity. The exploration of efficient electrocatal ...
ROYAL SOC CHEMISTRY2020
,
A highly stable nanocomposite of antioxidant activity was developed by immobilization of a superoxide dismutase-mimicking metal complex on copolymer-functionalized nanoclay. The layered double hydroxide (LDH) nanoclays were synthesized and surface modifica ...
2019
,
The carbonic anhydrase inhibitor acetazolamide (AcmH2) reacted with [(η6-p-cymene)RuCl(μ-Cl)]2 to afford [(η6-p-cymene)RuCl2(κN-AcmH2)], 1A, in near-quantitative yield. In methanol, 1A exists in equilibrium with 1B, being probably a coordination isomer, as ...
2018
The work presented in this thesis entails the synthesis and characterisation of new iron(II) tris(dioxime) clathrochelate complexes functionalised with apical capping groups suitable for supramolecular applications, and their subsequent incorporation into ...
EPFL2015
,
One large gap in research related to hybrid org./inorg. frameworks pertains to the inability to rationally design materials with targeted structural features and hence properties, a problem that stems from a lack of knowledge of their crystn. processes. Li ...
American Chemical Society2015
, ,
Metal org. frameworks (MOFs) are cryst. materials that contain metal-ions or metal-ion clusters as nodes and org. ligands as linkers to form 1-, 2-, and 3-D structures. In addn. to their convenient modular synthesis and chem. tunability, this class of mate ...
American Chemical Society2015
, ,
Metal-organic frameworks (MOFs) are a class of porous materials prepared by the self-assembly of metal ions or clusters with organic ligands. The unique characteristics of MOFs, including structural tunability, high surface areas, low densities and tailore ...
