Conjugated systemIn theoretical chemistry, a conjugated system is a system of connected p-orbitals with delocalized electrons in a molecule, which in general lowers the overall energy of the molecule and increases stability. It is conventionally represented as having alternating single and multiple bonds. Lone pairs, radicals or carbenium ions may be part of the system, which may be cyclic, acyclic, linear or mixed. The term "conjugated" was coined in 1899 by the German chemist Johannes Thiele.
Physical ReviewPhysical Review is a peer-reviewed scientific journal established in 1893 by Edward Nichols. It publishes original research as well as scientific and literature reviews on all aspects of physics. It is published by the American Physical Society (APS). The journal is in its third series, and is split in several sub-journals each covering a particular field of physics. It has a sister journal, Physical Review Letters, which publishes shorter articles of broader interest.
Rabi cycleIn physics, the Rabi cycle (or Rabi flop) is the cyclic behaviour of a two-level quantum system in the presence of an oscillatory driving field. A great variety of physical processes belonging to the areas of quantum computing, condensed matter, atomic and molecular physics, and nuclear and particle physics can be conveniently studied in terms of two-level quantum mechanical systems, and exhibit Rabi flopping when coupled to an optical driving field.
QuasiperiodicityQuasiperiodicity is the property of a system that displays irregular periodicity. Periodic behavior is defined as recurring at regular intervals, such as "every 24 hours". Quasiperiodic behavior is a pattern of recurrence with a component of unpredictability that does not lend itself to precise measurement. It is different from the mathematical concept of an almost periodic function, which has increasing regularity over multiple periods. Climate oscillations that appear to follow a regular pattern but which do not have a fixed period are called quasiperiodic.
Hückel's ruleIn organic chemistry, Hückel's rule predicts that a planar ring molecule will have aromatic properties if it has 4n + 2 π electrons, where n is a non-negative integer. The quantum mechanical basis for its formulation was first worked out by physical chemist Erich Hückel in 1931. The succinct expression as the 4n + 2 rule has been attributed to W. v. E. Doering (1951), although several authors were using this form at around the same time.
