Nitrogen, Phosphorus, and Sulfur Co-Doped Hollow Carbon Shell as Superior Metal-Free Catalyst for Selective Oxidation of Aromatic Alkanes
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The electrochemical reduction of CO2 to higher hydrocarbons is a very challenging process that has high potential for the storage of large amounts of renewable energy with a high gravimetric and volumetric energy density. The distribution of hydrocarbons f ...
Real-world vanadium-based catalysts for the selective catalytic reduction (SCR) of NO with NH3 are occasionally exposed to high temperatures, which can induce catalyst aging. In this work, a 2.0 wt% V2O5/WO3-TiO2 catalyst based on commercial WO3-TiO2 was l ...
Rising level of carbon dioxide (CO2) is a significant contributor to global warming and poses a major concern in modern society and environment. Anthropogenic activities such as fossil fuel combustion, cement production and deforestation are the primary ca ...
The main aim of this dissertation is to study the catalytic aspects of very small transition metal clusters supported on h-BN/Rh(111). The catalytic reactions of interest were ammonia synthesis and CO oxidation on mass selected and soft landed iron and pla ...
Our reliance on fossil fuels, which is unsustainable due to dwindling reserves, has led to various environmental issues. Lignocellulosic biomass could serve as a renewable source of carbon and energy for the production of fuels and chemicals. While several ...
The industrial production of aromatic amines, essential intermediates for the synthesis of several drugs, dyes, pigments and agrochemicals, requires the use of heterogeneous catalysis. These molecules were formerly produced by the Béchamp reduction, a non- ...
Log wood burning is a significant source of volatile organic compounds including aromatic hydrocarbons (ArHC). ArHC are harmful, are reactive in the ambient atmosphere, and are important secondary organic aerosol (SOA) precursors. Consequently, SOA represe ...
Sn-beta zeolites prepared using different recipes feature very different catalytic activities for aqueous phase glucose isomerization, suggesting the presence of different active sites. A systematic study of the morphology and atomic-level structure of the ...
Controlled mixtures of novel Mg-based metal-organic frameworks (MOFs) were prepared, with H+ or K+ as counterions. A linear relation was found between synthesis pH and K/H ratio in the resultant mixture, establishing the tunability of the synthesis. Upon p ...
Metal organic supramolecular chemistry on surfaces has matured to a point where its underlying growth mechanisms are well understood and structures of defined coordination environments of metal atoms can be synthesized in a controlled and reproducible proc ...