Infrared Vibrational Molecular Hybridization with a Single Optical Antenna
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Optical sensors based on the interaction between molecular vibrations and mid infrared radiations attracted high attentions in the last decades. In this study, we present the development of a waveguide evanescent field sensor based on the absorption spectr ...
The plasmonic systems used in surface-enhanced Raman scattering are shown to be quivalent to optomechanical cavities. The new backaction force of the plasmon on the molecular vibration could lead to coherent amplification of vibrational motion. ...
Wave packet propagation succeeding electron transfer (ET) from alizarin dye molecules into the nanocrystalline TiO2 semiconductor has been studied by ultrafast transient absorption spectroscopy. Because of the ultrafast time scale of the ET reaction of abo ...
The exceptional enhancement of Raman scattering by localized plasmonic resonances in the near field of metallic nanoparticles, surfaces or tips (SERS, TERS) has enabled spectroscopic fingerprinting down to the single molecule level. The conventional explan ...
The zero,-field splitting (ZFS) parameters of the Mn(EDTA)(H2O).2H(2)O. and [Mn(MeNO(2)A)(H2O)].2H(2)O systems were estimated by using DFT and ab initio CASSCF/NEVPT2 calculations (EDTA = (ethane-1,2-41bis(azanetriy1))tetraatetate; MeNO2A = 2,2'-(7-m ...
The present review on light emission stimulated by electrons tunneling inelastically through a junction formed by a sample and a tip of a scanning tunneling microscope (STM) focusses on the most relevant results obtained for a variety of systems, including ...
Since the invention of optical fiber cable data transmission using light has become ubiquitous in the past years. Nonlinear optical effects, which are hardly noticed in our daily life, have become crucial and highly influential for the design and performan ...
The plasmon enhancement of molecular hyper-Raman scattering, the nonlinear counterpart of Raman scattering, which involves the absorption of two fundamental photons, is investigated with emphasis on low energy molecular vibrations. The two-photon excitatio ...
Future photonic circuits with the capability of high-speed data processing at optical frequencies will rely on the implementation of efficient emitters and detectors on the nanoscale. Towards this goal, bridging the size mismatch between optical radiation ...
Motivated by the fabrication potential of multi-walled carbon nanotube structures, we numerically investigated a paired structure consisting of two metallic spheres each grown on one end of a multi-walled nanotube. The paired two-segmented structure is cap ...