Publication
Atomic bonding effects in annular dark field scanning transmission electron microscopy. I. Computational predictions
Related publications (60)
Self-Assembly of N-Rich Triimidazoles on Ag(111): Mixing the Pleasures and Pains of Epitaxy and Strain
Christian Wäckerlin, Ulrich Aschauer, Xing Wang, Mehdi Heydari
In the present report, homochiral hydrogen-bonded assemblies of heavily N-doped (C9H6N6) heterocyclic triimidazole (TT) molecules on an Ag(111) substrate were investigated using scanning tunneling microscopy (STM) and low energy electron diffraction (LEED) ...
Washington2023Double-bond delocalization in non-alternant hydrocarbons induces inverted singlet-triplet gaps
Marc Hamilton Folkmann Garner, Jacob Terence Blaskovits
Molecules where the first excited singlet state is lower in energy than the first excited triplet state have the potential to revolutionize OLEDs. This inverted singlet-triplet gap violates Hund's rule and currently there are only a few molecules which are ...
ROYAL SOC CHEMISTRY2023Double-bond delocalization in non-alternant hydrocarbons induces inverted singlet-triplet gaps
Marc Hamilton Folkmann Garner, Jacob Terence Blaskovits
Molecules where the first excited singlet state is lower in energy than the first excited triplet state have the potential to revolutionize OLEDs. This inverted singlet-triplet gap violates Hund's rule and currently there are only a few molecules which are ...
ROYAL SOC CHEMISTRY2023Mechanistic Insight into Supramolecular Polymerization in Water Tunable by Molecular Geometry
Supramolecular self-assembly in water based on non-covalent bonding is attracting major attention due to the potential of hydrogels and aqueous polymers in biomedical applications. Although supramolecular polymerization in organic solvents is well establis ...
CHINESE CHEMICAL SOC2022C-C bond activation enabled by dyotropic rearrangement of Pd(iv) species
Qian Wang, Jieping Zhu, Hua Wu, Jian Cao
The weak carbon-metal bond combined with the kinetic inertness of the carbon-carbon bond renders metal-catalysed C-C bond activation to be highly challenging. Most of the reported C-C bond activation methodologies involve strain-releasing cleavage of small ...
NATURE RESEARCH2021DORI Reveals the Influence of Noncovalent Interactions on Covalent Bonding Patterns in Molecular Crystals Under Pressure
Berend Smit, Benjamin André René Meyer, Senja Dominique Barthel, Laurent Alexis Clément Vannay, Amber Kashan Mace
The study of organic molecular crystals under high pressure provides fundamental insight into crystal packing distortions and reveals mechanisms of phase transitions and the crystallization of polymorphs. These solid-state transformations can be monitored ...
AMER CHEMICAL SOC2019Small Molecule Activation by Multimetallic Uranium Complexes
The development of new processes for the selective and sustainable transformation of abundant small molecules constitutes one of the major research areas in inorganic and organometallic chemistry. These molecules as CO2, CO, N2 and H2 are abundant reservoi ...
EPFL2019Pivotal Role of the Basic Character of Organic and Salt Catalysts in C-N Bond Forming Reactions of Amines with CO2
Paul Joseph Dyson, Martin Hulla
Organocatalysts promote a range of C-N bond forming reactions of amines with CO2. Herein, we review these reactions and attempt to identify the unifying features of the catalysts that allows them to promote a multitude of seemingly unrelated reactions. Ana ...
2019Soft Self-Healing Nanocomposites
Véronique Michaud, Yves Leterrier, Sravendra Rana
This review article provides an overview of the research and applications of soft self-healing polymers and their nanocomposites. A number of concepts based on physical and chemical interactions have been explored to create dynamic and reversible gel and e ...
FRONTIERS MEDIA SA2019Direct observation of photo-mechanical stiffness in alkanethiol-capped gold nanoparticles supracrystals by ultrafast small-angle electron diffraction
Francesco Stellacci, Fabrizio Carbone, Giulia Fulvia Mancini, Tatiana Latychevskaia, Javier Reguera Gomez, Francesco Pennacchio
We demonstrate that ultrastiff bonding between nanoparticles can be engineered by ad hoc assemblies of ligands, reaching strengths comparable to that of strong covalent bonds. Our observation relies on femtosecond small-angle electron diffraction. ...
E D P SCIENCES2019