Vibrational energy transfer near a dissociative adsorption transition state: State-to-state study of HCl collisions at Au(111)
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The Cold chopper and CAMEA spectrometers are in many ways equivalent. One uses several incoming energies combined with a continuous outgoing energy band while the other use a continuous incoming band and several outgoing energies, and both have big angular ...
The dynamics and bonding of the complex hydride LiBH4 have been investigated by vibrational spectroscopy and density functional theory (DFT). The combination of infrared, Raman, and inelastic neutron-scattering (INS) spectroscopies on hydrided and deuterat ...
CAMEA (Countinuous Angle Multiple Energy Analyser) is a new concept for analysing inelastically scattered neutrons with high efficiency. It contains many (up to 10) vertically focusing analyser arrays behind each other, analysing the scattered neutrons wit ...
Quantum state-resolved reactivity measurements probe the role of vibrational symmetry on the vibrational activation of the dissociative chemisorption of CH4 on Pt(111). IR–IR double resonance excitation in a molecular beam is used to prepare CH4 in all thr ...
A lamella of uranium dioxide (similar to 10 x similar to 10 x similar to 0.02-0.20 mu m) was produced by focused ion beam for transmission electron and electron energy loss spectroscopy (EELS) examinations. This sample allows quantitative analysis of the E ...
The dissociative chemisorption of CH4 on Pt(111) was studied using quantum state-resolved methods at a surface temperature (Ts) of 150 K where the nascent reaction products CH3(ads) and H(ads) are stable and accumulate on the surface. Most previous experim ...
We present a comparison between sum frequency scattering (SFS) and reflection mode sum frequency generation (R-SFG). We have used scattering theory to describe both scattering experiments as well as reflection mode experiments. The interfacial vibrational ...
The enhancement of fluorescence and Raman scattering by plasmonic nanostructures is studied theoretically with special focus on the effects of the observed molecule's properties and the realistic geometry of the plasmonic nanostructure. Numerical experimen ...
We present a stereodynamics study of the dissociative chemisorption of vibrationally excited methane on the (100), (110), and (111) planes of a nickel single crystal surface. Using linearly polarized infrared excitation of the antisymmetric C–H stretch nor ...
In this thesis, I describe the design and first applications of a new molecular-beam/surface-science ultra-high vacuum apparatus. The new machine combines rovibrational state-selective infrared pumping of gas-phase reactants with reflection absorption infr ...