Crystal Engineering of Polymeric Structures with Dative Boron–Nitrogen Bonds: Design Criteria and Limitations
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This thesis explores different aspects of DNA topology through experimental and numerical techniques. Topology is a vast mathematical field, that deals with the spatial properties of objects undergoing continuous deformations, but here it is restricted to ...
The aim of this thesis was to explore the statistical physics and the mechanical properties of individual biomolecules, to study their interactions, and to develop new techniques based on atomic force microscopy (AFM). First, we exploit the high resolution ...
Supersilyl alk. metals (alkali supersilanides) tBu3SiM without or with donors (Do) like ethers, amines, arom. hydrocarbons are easily obtained by the action of alk. metals M on supersilyl halides tBu3SiX above room temp. in alkanes or donor-solvents like T ...
The rheological behavior of two hyperbranched polymer/silica suspensions with different dispersion states, surface chemistries, and concentrations of the silica nanoparticles was investigated in terms of viscoelastic properties, activation energy for visco ...
This feature article provides a compilation of tools available for preparing well-defined peptide/protein–polymer conjugates, which are defined as hybrid constructs combining (i) a defined number of peptide/protein segments with uniform chain lengths and d ...
A series of imidazolium dicarboxylic acids have been prepd. from the reaction of the 1,3-bis(carboxymethyl)imidazolium zwitterion with the Bronsted acids HX (X = F, Br, Cl, ClO4). The structures of these acids have been established in the solid ...
The preparation of synthetic polymers with exact control over chain length and monomer sequence is one of the long-standing challenges in polymer science. Nature perfectly masters the synthesis of high molecular weight, perfectly monodisperse polypeptides ...
Heteroditopic monomers containing an arylboronate ester and a dialkyl-4-aminopyridine group aggregate via dative boron–nitrogen bonds to give main chain supramolecular polymers. The degree of polymerization can be tuned by changing the electronic and steri ...
The partial molar volume, .hivin.V, and the partial sp. vol., .hivin.n, were estd. for more than 25 polyelectrolyte structures. The materials investigated by d. measurements in highly dild. aq. solns. (c < 10-2 monomol/L) included both synthetic polyelectr ...
This paper reports on the cell uptake and trafficking properties of a series of non-covalent polymer-drug conjugates. These nanomedicines are composed of a poly(N-(2-hydroxypropyl)methacrylamide) backbone functionalized with multiple copies of a drug. The ...