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Nuclear Magnetic Resonance (NMR) is one of the most versatile techniques since it enables the characterization of solid, liquid and gaseous systems in a plethora of in-vitro and in-vivo experiments. Despite its multidisciplinary scope, it still suffers fro ...
Nuclear magnetic resonance (NMR) was discovered in the first half of the 20th century. Today, neither analytical chemistry without NMR spectroscopy nor medical diagnostics without magnetic resonance imaging (MRI) could be imagined. A magnetic resonance sig ...
In dynamic nuclear polarisation (DNP), also called hyperpolarisation, a small amount of unpaired electron spins is added to the sample containing the nuclear spins, and the polarisation of these unpaired electron spins is transferred to the nuclear spins b ...
We introduce a new approach to improve structural and dynamical determination of large metalloproteins using solid-state nuclear magnetic resonance (NMR) with H-1 detection under ultrafast magic angle spinning (MAS). The approach is based on the rapid and ...
Dissolution dynamic nuclear polarization (DNP) provides a way to tremendously improve the sensitivity of nuclear magnetic resonance experiments. Once the spins are hyperpolarized by dissolution DNP, the radicals used as polarizing agents become undesirable ...
The transverse relaxation rates R (2) = 1/T (2) of protons can be determined by spin-echo sequences with multiple refocusing pulses using moderate radio-frequency field strengths and properly chosen inter-pulse delays so as to suppress echo modulations due ...
Recent discoveries highlighted the activity, and the intrig-uing, mechanistic features of NIDCl5 as a molecular catalyst for the cycloaddffion, of CO2 and epoxides under ambient cooditions. This hag inSpired the preparation, of novel silica-supported Nb sp ...
Many of the functions and applications of advanced materials result from their interfacial structures and properties. However, the difficulty in characterizing the surface structure of these materials at an atomic level can often slow their further develop ...
Grafting (ArO)(2)W(=O)(=CHtBu) (ArO = 2,6-mesitylphenoxide) on partially dehydroxylated silica forms mostly [( SiO)W(=O)(=CHtBu)(OAr)] along with minor amounts of [( SiO)W(=O)(CH(2)tBu)-(OAr)(2)] (20%), both fully characterized by elemental analysis and IR ...
Sensitivity in Nuclear Magnetic Resonance (NMR), especially in solid-state NMR, has always been a challenging and important issue and thus a motivation for new developments. The magnetic field B0, the gyromagnetic ratios of the observed nuclei, as well as ...
