Experimental and theoretical approach to the study of CO2 adsorption in an extensive family of metal-organic frameworks
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Analysis of the CO2 adsorption properties of a well-known series of metal-organic frameworks M-2(dobdc) (dobdc(4-) = 2,5-dioxido-1,4-benzenedicarboxylate; M = Mg, Mn, Fe, Co, Ni, Cu, and Zn) is carried out in tandem with in situ structural studies to ident ...
Owing to their high surface areas, tunable pore dimensions, and adjustable surface functionality, metal-org. frameworks (MOFs) can offer advantages for a variety of gas storage and gas sepn. applications. In an effort to help curb greenhouse gas emissions ...
Materials exhibiting reversible hydrogen adsorption with high gravimetric and volumetric capacities are sought for use in on-board storage systems of hydrogen fuel cell-powered vehicles. Microporous metal-org. frameworks with high internal surface areas ha ...
Owing to their high surface areas, tunable pore dimensions, and adjustable surface functionality, metal-org. frameworks (MOFs) can offer advantages for a variety of gas storage and gas sepn. applications. In an effort to reduce the major energy requirement ...
Porous polymer networks (PPNs) are a class of porous materials of particular interest in a variety of energy-related applications because of their stability, high surface areas, and gas uptake capacities. Computationally derived structures for five recentl ...
This paper studies about metal-org. frameworks for on-board storage of hydrogen and natural gas. The paper studies on synthesis of thermally-robust, high-surface area materials with a high concn. of open metal coordination sites. ...
Hydrogen is often regarded as a viable clean burning alternative to our current petroleum based fuel sources as a result of its high gravimetric energy d. and renewable nature. Furthermore, H2 has received significant attention as a transportation fuel. A ...
The metal-org. frameworks M2(dobdc) (dobdc4- = 2,5-dioxido-1,4-benzenedicarboxylate, MOF-74, CPO-27) (M = Mg, Mn, Fe, Co, Ni, Zn) have shown considerable promise for a no. of gas storage and sepn. applications. These have included CO2/N2, CO2/H2, O2/N2, an ...
High atm. CO2 levels, resulting largely from combustion of fossil fuels, and its undesirable impact on global climate has sparked considerable interest in cleaner energy sources. While energy transitions are historically slow, technol. solns. for mitigatio ...
A significant redn. in the energy costs assocd. with the cryogenic sepn. of ethylene-ethane and propylene-propane mixts. could potentially be realized through the use of selective solid adsorbents that operate at higher temps. The metal-org. frameworks M2( ...
