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This paper studies about metal-org. frameworks for on-board storage of hydrogen and natural gas. The paper studies on synthesis of thermally-robust, high-surface area materials with a high concn. of open metal coordination sites. ...
The development of nanostructured materials with predictable and controllable connectivity and functionalities has sparked a multitude of research directions. We have been studying emerging metal-org. framework (MOFs) systems and their adsorption propertie ...
Developments in modern neutron spectroscopy have led to typical sample sizes decreasing from few cm to several mm in diameter samples. We demonstrate how small samples together with the right choice of analyser and detector components makes distance collim ...
Cationic N,O-chelating dendrimers functionalised on the periphery with RAPTA-like (ruthenium(II)-arene-1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane) moieties have been synthesised and characterised using NMR and IR spectroscopy, elemental analysis and MAL ...
The dynamics and bonding of the complex hydride LiBH4 have been investigated by vibrational spectroscopy and density functional theory (DFT). The combination of infrared, Raman, and inelastic neutron-scattering (INS) spectroscopies on hydrided and deuterat ...
Using small angle neutron scattering, the anisotropy of the magnetic vortex lattice (VL), in the heavily hole-doped pnictide superconductor KFe2As2, was studied. Well-ordered VL scattering patterns were measured with fields applied in directions between B∥ ...
In this work, a flexible metal-org. framework (MOF) (nickname BPene), [Ni'(L)Ni(CN)4]n (L=1,2-bis(4-pyridyl)-ethylene) that shows reversible structural transitions between low porosity and high porosity phases during the adsorption and desorption of CO2 ha ...
Using small angle neutron scattering, the anisotropy of the magnetic vortex lattice (VL), in the heavily hole-doped pnictide superconductor KFe2As2, was studied. Well-ordered VL scattering patterns were measured with fields applied in directions between B ...
Metal-organic frameworks (MOFs), a class of porous materials, are of particular interest in gas storage and separation applications due largely to their high internal surface areas and tunable structures. MOF-5 is perhaps the archetypal MOF; in particular, ...
Materials exhibiting reversible hydrogen adsorption with high gravimetric and volumetric capacities are sought for use in on-board storage systems of hydrogen fuel cell-powered vehicles. Microporous metal-org. frameworks with high internal surface areas ha ...
