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On Decoupling Chemical Reaction Systems

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Hypervalent Iodine: New Reagents and Functionalization of Peptides

Eliott Hugo Joran Le Du

Alkynes are found in a multitude of natural or synthetic bioactive compounds. In addition to the capacity of these chemical motifs to impact the physicochemical properties of a molecule of interest, the well-established reactivity of alkynes makes them ...

EPFL2023

Kinetic Network Modeling of the Catalytic Upgrading of Biomass's Acetate Fraction to Aromatics

Jeremy Luterbacher, Jher Hau Yeap, Bartosz Rozmyslowicz, Ahmed Mohamed Ibrahim Elkhaiary

The acetate fraction is the fourth most abundant fraction by weight in many plant species and can be easily extracted as acetic acid in high yields. We have previously shown that acetic acid obtained from steam pretreated beech wood could be upgraded in a ...

Washington2023

Complexation Strategies towards Challenging Group 9 Metal Cyclopentadienyl Scaffolds

Aragorn Nathan Laverny

Cyclopentadienyl (Cp) metal complexes and their chiral counterparts (CpX) have enabled the development of challenging C-H activation transformations. While major progresses were made in developing new chiral CpX complexes and exploring their reactivity, th ...

EPFL2023

Unbiased likelihood-based estimation of Wright-Fisher diffusion processes

In this paper we propose an unbiased Monte Carlo maximum likelihood estimator for discretely observed Wright-Fisher diffusions. Our approach is based on exact simulation techniques that are of special interest for diffusion processes defined on a bounded d ...

MCQMC2023

Efficient AC electrothermal flow (ACET) on-chip for enhanced immunoassays

Martinus Gijs, Diego Gabriel Dupouy, Muaz Salama Abdelmonem Draz

Biochemical reaction rates in microfluidic systems are known to be limited by the diffusional transport of reagents, leading often to lowered sensitivity and/or longer detection times in immunoassays. Several methods, including electrically powering electr ...

ROYAL SOC CHEMISTRY2023

Methods of trajectory estimation in challenging mapping scenarios

Aurélien Arnaud Brun

With the aim of improving trajectory estimation and point cloud georeferencing in the scope of Kinematic Laser Scanning (ALS), we recently proposed a novel procedure leveraging the automated extraction of reliable 3D point to point correspondences and thei ...

2023

Almost cyclic regular semisimple elements in irreducible representations of simple algebraic groups

Donna Testerman

Let G be a simple linear algebraic group defined over an algebraically closed field of characteristic p ≥ 0 and let φ be a nontrivial p-restricted irreducible representation of G. Let T be a maximal torus of G and s ∈ T . We say that s is Ad-regular if α(s ...

2023

Improving Standard-Cell Design Flow using Factored Form Optimization

Giovanni De Micheli, Alessandro Tempia Calvino

Factored form is a powerful multi-level representation of a Boolean function that readily translates into an implementation of the function in CMOS technology. In particular, the number of literals in a factored form correlates strongly with the number of ...

New York2023

Writing and Drawing Inventions: Patents and Technology in France and the United States (18th-19th centuries)

Jérôme Baudry

Description (through texts, images, models or samples) played a central role in the patent regimes that emerged in the eighteenth century, first in England, later in the United States and in France. Description ensured that the contract—protection in excha ...

2023

Neural Distributed Image Compression with Cross-Attention Feature Alignment

Ali Garjani

We consider the problem of compressing an information source when a correlated one is available as side information only at the decoder side, which is a special case of the distributed source coding problem in information theory. In particular, we consider ...

IEEE COMPUTER SOC2023