Dark Photocatalysis: Storage of Solar Energy in Carbon Nitride for Time-Delayed Hydrogen Generation
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This thesis deals with different aspects of renewable energy transformation and storage concepts and connects them. Although renewable energy installations are growing worldwide, their use is limited by storage technologies. As such, water splitting for hy ...
Solar-driven high-temperature electrolysis (HTE) and thermochemical cycles (TCC) are two promising pathways for fuel processing and energy storage, which are considered in this thesis. The goals of this thesis are: i) offering engineering guidelines at sys ...
At the dawn of the 21st century, mankind is facing an important energy challenge. Future energy demand can only be met by large scale exploitation of renewable energy resources. Solar energy is abundant, with a sufficient capacity for the growing energy de ...
Nowadays, the efficient, stable, and scalable conversion of solar energy into chemical fuels represents a great scientific, economic, and ethical challenge. Amongst the available candidate technologies, photoelectrochemical water splitting potentially has ...
In oxidative electrochemical organic synthesis, radical intermediates are often oxidized to cations on the way to final product formation. Herein, we describe an approach to transform electrochemically generated organic radical intermediates into neutral p ...
Solution processable organic semiconductors are well-established as high-performance materials for inexpensive and scalable solar energy conversion in organic photovoltaic (OPV) devices, but their promise in the economic conversion of solar energy into che ...
Synthetic studies of bimetallic uranium nitride complexes with the N(SiMe3)(2) ligand have generated a new nitride complex of U(III), which is highly reactive toward C-H bonds and H-2. Treatment of the previously reported U(IV)/U(IV) nitride complex [Na(DM ...
Rapidly increasing levels of atmospheric carbon dioxide and their damaging impact on the global climate system raise doubts about the sustainability of the fossil resource based energy system. Meanwhile, raising living standards and increasing global popul ...
Splitting water to produce hydrogen (H2) fuel appears very promising to address the challenges of solar energy storage and global warming as the only by-product generated is oxygen (O2). An alternative strategy, called batch water-splitting, based on Inter ...
Concurrent solar generation of hydrogen and CO through photoelectrochemical (PEC) water and CO2 electrolysis, and the subsequent use of the product gas mixture in conventional Fischer-Tropsch processes, has the potential to provide a flexible pathway for d ...