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Hyperpolarization of nitrogen-15 nuclei by cross polarization and dissolution dynamic nuclear polarization

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Dnp biosensor

Jean-Philippe Ansermet, Jonas Milani

Method for detecting a change in molecular tumbling of an electron-spin labelled system (1) in solution. Nuclear spins of the entire solution are measured in solution using Overhauser dynamic nuclear polarization in a first reference measurement, and then ...

2022

Mechanistic studies of DNP and applications of hyperpolarized probes to study renal physiology and metabolism

Alice Radaelli

Dissolution dynamic nuclear polarization (dDNP) is a powerful technique that enhances the magnetic resonance signal of nuclear spins by several orders of magnitude. DNP relies on the principle of cross-relaxation by electron spins driven out of equilibrium ...

EPFL2021

Solid-state nuclear magnetic resonance (NMR) spectroscopy is an atomic-level method to determine the chemical structure, 3D structure and dynamics of solids and semi-solids. This Primer summarizes the basic principles of NMR spectroscopy as applied to the ...

SPRINGERNATURE2021

Solid-state NMR can provide information about the atomic level structure and dynamics of materials. It directly probes symmetry and structure at nuclear sites, and is especially useful for investigation of disordered or amorphous solids that lack long rang ...

EPFL2021

Dissolution-DNP is a method to boost liquid-state NMR sensitivity by several orders of magnitude. The technique consists in hyperpolarizing samples by solid-state dynamic nuclear polarization at low temperature and moderate magnetic field, followed by an i ...

SPRINGER2020

Maximizing nuclear hyperpolarization in pulse cooling under MAS

David Lyndon Emsley, Brennan James Walder, Nicolas Luc Matthey

It has recently been shown how dynamic nuclear polarization can be used to hyperpolarize the bulk of proton-free solids. This is achieved by generating the polarization in a wetting phase, transferring it to nuclei near the surface and relaying it towards ...

ACADEMIC PRESS INC ELSEVIER SCIENCE2019

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Crystalline organic semiconducting materials are much in demand for multiple electronic and optoelectronic device applications. Here, solution grown ultrathin rhombic crystals of a trimethine carbocyanine anionic dye are used to establish relationships bet ...

Royal Society of Chemistry2018

Dendritic polarizing agents for DNP SENS

David Lyndon Emsley, David Benjamin Roger Antoine Gajan

Dynamic Nuclear Polarization Surface Enhanced NMR Spectroscopy (DNP SENS) is an effective method to significantly improve solid-state NMR investigation of solid surfaces. The presence of unpaired electrons (polarizing agents) is crucial for DNP, but it has ...

Royal Soc Chemistry2017

Magnetic structure of Ba(TiO)Cu4(PO4)4 probed using spherical neutron polarimetry

Henrik Moodysson Rønnow, Luc Testa, Peter Babkevich, Gregory Scott Tucker

The antiferromagnetic compound Ba(TiO)Cu4(PO4)4 contains square cupola of corner-sharing CuO4 plaquettes, which were proposed to form effective quadrupolar order. To identify the magnetic structure, we have performed spherical neutron polarimetry measureme ...

2017

Reactive surface organometallic complexes observed using dynamic nuclear polarization surface enhanced NMR spectroscopy

David Lyndon Emsley, Jasmine Viger-Gravel, David Benjamin Roger Antoine Gajan

Dynamic Nuclear Polarization Surface Enhanced NMR Spectroscopy (DNP SENS) is an emerging technique that allows access to high-sensitivity NMR spectra from surfaces. However, DNP SENS usually requires the use of radicals as an exogenous source of polarizati ...

Royal Soc Chemistry2017