Origins of the macroscopic symmetry breaking in centrosymmetric phases of perovskite oxides
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The influence of annealing between the Curie transition and the melting point of solvent cast polyvinylidene fluoride trifluoroethylene copolymer films on the crystalline structure, mechanical and electrical properties, and oxygen permeability is investiga ...
Flexoelectricity-the coupling between polarization and strain gradients-is a universal effect allowed by symmetry in all materials. Following its discovery several decades ago, studies of flexoelectricity in solids have been scarce due to the seemingly sma ...
The flexoelectric effect is the response of electric polarization to a mechanical strain gradient. It can be viewed as a higher-order effect with respect to piezoelectricity, which is the response of polarization to strain itself. However, at the nanoscale ...
The stability of electrically induced long-range ferroelectric order in a relaxor 0.94(Bi1/2Na1/2) TiO3-0.06BaTiO(3) ceramic material has been investigated by temperature-dependent X-ray diffraction and electrical property measurements. The depolarization ...
The manner in which 90. ferroelectric-ferroelastic domains respond to changes in temperature has been mapped in BaTiO3 single crystals using atomic force microscopy. Domain periodicity remains unaltered until approximately 2 degrees C below the Curie tempe ...
Flexoelectric effect is the response of electric polarization to the mechanical strain gradient. At the nano-scale, where large strain gradients are expected, the flexoelectric effect becomes appreciable and may substitute piezoelectric effect in centrosym ...
This thesis consists of a theoretical analysis of charged domain walls in ferroelectrics based on Landau theory and the theory of semiconductors. First, the internal structure of a 180-degree charged domain wall is considered. It is shown that different re ...
This work was originally motivated by the search for high-temperature piezoceramic materials with low acoustic impedance and high electromechanical coupling. The temperature and pressure behavior of two PZT-based materials with engineered porosity, Pz31 & ...
We reveal a strong elastic interaction between nonferroelastic domain walls in ferroelectric thin films. This interaction, having no analogue in bulk materials, is governed by elastic fields that are associated with the domain walls and extends to distance ...
Longitudinal piezoelectric coefficient of a twinned ferroelectric perovskite material with an array of partially compensated head-to-head and tail-to-tail 90-degree domain walls has been studied by phase-field simulations in the framework of the Ginzburg-L ...