Nanoionics Phenomena and Devices with Oxide Thin Films
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Cr poisoning is a well-identified performance degradation process in solid oxide fuel cells (SOFC). While stainless steel (SS) interconnects have been identified to be a significant source of Cr, the Cr contribution from balance-of-plant (BoP) components l ...
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This thesis focuses on Cr-poisoning in solid oxide fuel cells (SOFC), which currently presents a key challenge for the development of this technology. By the implementation of dedicated experimental tools, this work offers a new access to, and comprehensio ...
Generating large force/displacement actuators at the millimeter and sub-millimeter scales remains an important challenge for microsystems engineers. One promising solution is to integrate high-energy density solid propellant fuels in microsystems (pyroMEMS ...
Recently, the development of micro-scale solid oxide fuel cells (µ-SOFCs) has become a promising research topic in the area of portable energy production. A µ-SOFC system, which can provide 1 to 2 W electrical power under an operating temperature of 550°C ...
Due to their high specific energy and energy density, micro-solid oxide fuel cells1,2 (µ-SOFCs) are seen as one of the technologies that could help satisfying the continuously increasing demand for electric energy in portable electronic devices. The µ-SOFC ...
Micro-solid oxide fuel cell (mu SOFC) structures with annular Pt electrodes have been fabricated by means of silicon micromachining. The annular cathodes contained a defined triple phase boundary (TPB) length, which allowed the derivation of the ionic curr ...
Strong coupling among external voltage, electrochemical potentials, concentrations of electronic and ionic species, and strains is a ubiquitous feature of solid statemixed ionic-electronic conductors (MIECs), the materials of choice in devices ranging from ...
This thesis focuses on the degradation pathways occurring in composite solid oxide fuel cell (SOFC) cathodes based on lanthanum-strontium manganite (LSM), combining modeling at the electrode level with experimental data. LSM composite electrodes are one of ...
