Protection Group Effects During α,γ-Diol Lignin Stabilization Promote High-Selectivity Monomer Production
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Our current energy production is convenient and simple, but it is not sustainable. The negative impacts on our environment are omnipresent in the form of smog, extinction of species, and global warming. A major challenge of our generation is the transition ...
Rapidly increasing levels of atmospheric carbon dioxide and their damaging impact on the global climate system raise doubts about the sustainability of the fossil resource based energy system. Meanwhile, raising living standards and increasing global popul ...
Methyltransferases (MTases) form a large family of enzymes that methylate a diverse set of targets, ranging from the three major biopolymers to small molecules. Most of these MTases use the cofactor S-adenosyl-l-Methionine (AdoMet) as a methyl source. In r ...
At the dawn of the 21st century, mankind is facing an important energy challenge. Future energy demand can only be met by large scale exploitation of renewable energy resources. Solar energy is abundant, with a sufficient capacity for the growing energy de ...
Securing our energy future while minimizing the associated environmental impacts is a challenging endeavor and the fundamental aspect of sustainable development. The choice of energy resource and the reduction of greenhouse gas emissions, primarily carbon ...
Formic acid is considered as one of the promising organic liquid hydrogen carriers for the next generation; it can offer a viable method for safe hydrogen transport. In this chapter, we introduce the potential of formic acid in terms of thermodynamics and ...
We described herein a simple approach for N-formylation with CO2 and hydrosilane reducing agents. Fluoride and hydroxide salts efficiently catalyzed the reaction, principally through activation of the hydrosilanes, which led to hydrosilane reactivities com ...
Pd(II)-catalyzed double cyclization of 1,2-diarylethynes bearing an N-methyl-N-[2-(methoxycarbonyl)ethyl]amino and an aminocarbonyl group at the ortho positions of the two aromatic rings afforded the tetracyclic N-[2-(methoxycarbonyl)-ethyl]indoloisoquinol ...
This year Mankind will release about 39 Gt carbon dioxide into the earth's atmosphere, where it acts as a greenhouse gas. The chemical transformation of carbon dioxide into useful products becomes increasingly important, as the CO2 concentration in the atm ...
Vicinal amino alcohols are important structural motifs of bioactive compounds. Reported herein is an efficient method for their synthesis based on the palladium-catalyzed oxy-alkynylation, oxy-arylation, or oxy-vinylation of allylic amines. High regio- and ...