Publication
Reversible Dihydrogen Activation and Hydride Transfer by a Uranium Nitride Complex
Related publications (33)
Facile CO Cleavage by a Multimetallic CsU2 Nitride Complex
Rosario Scopelliti, Marinella Mazzanti, Marta Falcone
Uranium nitrides are important materials with potential for application as fuels for nuclear power generation, and as highly active catalysts. Molecular nitride compounds could provide important insight into the nature of the uranium–nitride bond, but curr ...
2016Synthesis and Structure of Nitride-Bridged Uranium(III) Complexes
Rosario Scopelliti, Marinella Mazzanti, Lucile Sylvie Danielle Chatelain
The reduction of the nitride-bridged diuranium(IV) complex Cs[{U(OSi((OBu)-Bu-t)(3))(3)}(2)(mu-N)] affords the first example of a uranium nitride complex containing uranium in the +III oxidation state. Two nitride-bridged complexes containing the heteromet ...
American Chemical Society2016Chemoselective Hydrogenation and Transfer Hydrogenation of Aldehydes Catalyzed by Iron(II) PONOP Pincer Complexes
Rosario Scopelliti, Xile Hu, Simona Mazza
Iron-catalyzed hydrogenation has drawn much attention, yet the scope and chemoselectivity of iron catalysis warrant further improvement. Here we report new iron pincer complexes as chemoselective hydrogenation and transfer hydrogenation catalysts. Several ...
American Chemical Society2015Hydrogen Storage in the Carbon Dioxide - Formic Acid Cycle
Gabor Laurenczy, Cornel Fink, Mickael Montandon-Clerc
This year Mankind will release about 39 Gt carbon dioxide into the earth's atmosphere, where it acts as a greenhouse gas. The chemical transformation of carbon dioxide into useful products becomes increasingly important, as the CO2 concentration in the atm ...
Swiss Chemical Soc2015Metal-Free Catalyst for the Chemoselective Methylation of Amines Using Carbon Dioxide as a Carbon Source
Paul Joseph Dyson, Gabor Laurenczy, Felix Daniel Bobbink, Shoubhik Das
N-methylation of amines is an important step in the synthesis of many pharmaceuticals and has been widely applied in the preparation of other key intermediates and chemicals. Therefore, the development of efficient methylation methods has attracted conside ...
Wiley-V C H Verlag Gmbh2014A hybrid absorption-adsorption method to efficiently capture carbon
Berend Smit, Xiaoqi Zhang, Jin Wang, Yuqing Wu
Removal of carbon dioxide is an essential step in many energy-related processes. Here we report a novel slurry concept that combines specific advantages of metal-organic frameworks, ion liquids, amines and membranes by suspending zeolitic imidazolate frame ...
Nature Publishing Group2014Photoreduction of CO2 Using [Ru(bpy)2(CO)L]n+ Catalysts in Biphasic Solution/Supercritical CO2 Systems
Hubert Girault, Manuel Alejandro Méndez Agudelo, Kathryn Ellen Toghill, Patrick Voyame
The photosensitized reduction of carbon dioxide by the molecular catalyst [Ru(bpy)2(CO)L] is studied in a biphasic liquid-condensed gas system. Increasing pressure is shown to enhance the initial production rate and turnover number of the catalyst before d ...
Amer Chemical Soc2013Hydrogen Storage and Delivery: The Carbon Dioxide – Formic Acid Couple
Carbon dioxide and the carbonates, the available natural C-1 sources, can be easily hydrogenated into formic acid and formates in water; the rate of this reduction strongly depends on the pH of the solution. This reaction is catalysed by ruthenium(II) pre- ...
Schweizerische Chemische Gesellschaft2011Ruthenium-Catalyzed Hydrogenation of Bicarbonate in Water
Gabor Laurenczy, Matthias Beller
Hydrogenation of bicarbonates in water: By using a ruthenium-based catalytic system hydrogenation of sodium bicarbonate was achieved in water in comparable high TONs and yields. The hydrogenation of sodium bicarbonate takes place with the catalytic system ...
Wiley-VCH Verlag Berlin2010Thermo-economic analysis of chemical looping processes
Among the different ways of capturing carbon dioxide in industrial processes, chemical looping process is presented as an improvement in oxy-fuel combustion. Since carbon dioxide is directly generated with water in the process, there is no need of an addit ...
2010