On decoupling rate processes in chemical reaction systems - Methods and applications
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Reaction of Me3CCMe(OH)CR:CH2 (I; R = H) with Br2 or NBS in aq. medium resulted in rearrangement, yielding ketones Me3CCOCHMeCH2Br and MeCOCR(CH2Br)CMe3 (III) and the oxirane II. With I (R = F, Me), bromination gave only ketone III. Competition expts. show ...
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We identified the nature of the chemical reaction between silver and the cleaved surface of BiCaSrCuO at room temperature as a Bi-Ag reaction with Bi segregation, accompanied by interaction with the Sr atoms. Our synchrotron-radiation photoemission spectra ...
