Synthesis and Postpolymerization Modification of Fluorine-End-Labeled Poly(Pentafluorophenyl Methacrylate) Obtained via RAFT Polymerization
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This thesis is devoted to the study of the dispersion polymerization of methyl methacrylate in supercritical carbon dioxide (scCO2), using a poly(dimethylsiloxane) macromonomer (PDMS macromonomer) as stabilizer. Supercritical fluids (SCF) and SCF mixtures ...
With the recent development of fluorescent probes and new high-resolution microscopes, biological imaging has entered a new era and is presently having a profound impact on the way research is being conducted in the life sciences. Biologists have come to d ...
Monitoring biological relevant reactions on the single molecule level based on fluorescence spectroscopy techniques has become one of the most promising approaches for understanding a variety of phenomena in biophysics, biochemistry and life science. By ap ...
The bimetallic ruthenium complex [(1,3,5-C6H3i-Pr3)Ru(m-Cl)3RuCl(C2H4)(PCy3)] has been synthesized by reaction of [(1,3,5-C6H3i-Pr3)RuCl2)]2 with one equivalent of PCy3 in the presence of ethylene. It can be used as a catalyst precursor for the controlled ...
In order to describe the different events occurring during the anionic polymerization of polyamide 12 (PA12), a general concept of a time, temperature, and transformation (TTT) diagram was established and related to reactive processing conditions. Polymeri ...
A kinetic model for solid-state polycondensation of nylon-6 was developed by extrapolation of the melt chemistry to the amorphous phase of the solid polymer. In this way, a phenomenological description of the process was obtained that required examining al ...
Stimuli-responsive polymers have the unique property of undergoing a reversible phase transition. This property has attracted much interest for their application in the field of medicine and biotechnology, such as drug delivery systems. Linear polymers of ...
Pure and K-doped vanadia/titania catalysts have been studied by transient response method and in situ DRIFTS during toluene partial oxidn. They were characterized by FT-Raman spectroscopy, TPR, TPD of pyridine and XPS. In order to elucidate the role of dif ...
PVA coated and fluorescent dye (Cy3.5) functionalized vinyl alcohol/vinyl amine copolymer coated superparamagnetic iron oxide nanoparticles (SPION) were evaluated for systemic distribution and elimination after intraarticular injection in sheep. Observatio ...
The present PhD thesis deals with the high temperature polymerization of methyl methacrylate in a continuous pilot scale process. The major aim is to investigate the feasibility of a polymerization process for the production of PMMA molding compound at tem ...