Features of proteolytic properties of tetraphenylporphyrin complex with lanthanide group metals
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The redox chemistry of f-elements is drawing the attention of inorganic chemists due to their unusual reaction pathways. Notably low-valent f-element complexes have been shown to be able to activate small molecules such as CO2 and N2 in mild conditions. Co ...
Complexes of lanthanide (III) ions have been used in structural studies of biomolecules and as contrast agents (CA). Clinically approved CAs have only one water molecule in their first coordination sphere. Structure and water exchange rate of these complex ...
We present a systematic study of the ultrafast fluorescence with broadband detection and similar to 110 fs resolution of 5,10,15,20-tetraphenylporphin (TPP) and 2,3,7,8,12,13,17,18-oc-taethylporphin (OEP), with open 3d-shell metals. We also revisit the cas ...
Mendeleev in his first publication ordered the chemical elements following an apparent periodicity of properties such as atomic volume and valence. The reactivity of the elements was only studied systematically many years later. To illustrate the systemati ...
Calcium silicate hydrate (C-S-H) is the main hydrate phase in Portland cements. Its composition
varies depending on the Ca/Si ratio and on the presence of other ions such as aluminium (called CA-
S-H) or alkalis.
This thesis aimed to study the compositi ...
Bromate formation from the reaction between chlorine and bromide in homogeneous solution is a slow process. The present study investigated metal oxides enhanced bromate formation during chlorination of bromide-containing waters. Selected metal oxides enhan ...
We report Shubnikov-de Haas oscillation measurements within the high magnetic field (μ0H>39 T) magnetically polarized regime of URu2Si2, made possible using mesoscopic samples prepared by means of focused ion beam lithography. A significant change in the F ...
The lanthanide(III) complexes formed with the tri- and tetraacetate derivatives of bis(aminomethyl)phosphinic acid, L1 and L2, respectively, have been studied by pH potentiometry, spectrophotometry and 1H and 17O NMR spectroscopy. L1 forms [Ln(L1)], [Ln(L1 ...
A better understanding of silica dissolution-precipitation reactions at high pH aqueous solutions allows for promotion of favorable (e.g., pozzolanic) reactions and mitigation of deleterious (e.g., alkali-silica) reactions in concrete. In this paper, the k ...
The surface chemistry of synthetic calcium aluminosilicate glasses exposed to aqueous solutions of varying pH was described using zeta potential measurements and batch surface titrations. Element release and proton consumption were measured to characterize ...
