Recent Advances in Catalytic Enantioselective Rearrangement
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Transfer of chirality during the build-up of molecules has been applied innumerable times in organic chemistry since the end of the 19th century, when it was introduced in the so-called asymmetric synthesis by E. Fischer. Although analogous reactions were ...
Two short syntheses of D-N-Boc-3,5-bis(isopropyloxy)-4-methoxyphenylglycine, a central unit of vancomycin type antibiotics, have been developed. A diastereoselective Strecker amination reaction using (S)-phenylglycinol as a chiral inducer was the key step ...
A review with >50 refs. on a macrocyclization method based on intramol. SNAr reaction developed recently in the author's lab. Mild conditions, high yield and versatility are the characteristic features of the method. Application to the synthesis of 14-, 16 ...
Biflavones I (R = Ph, 4-MeOC6H4) were prepd. from diketone II (R1 = Me, R2 = H) via rearrangement of II (R1 = Bz, 4-MeOC6H4CO, R2 = H) to II (R1 = H, R2 = Bz, 4-MeOC6H4CO). [on SciFinder (R)] ...
