New insights into the effect of nitrogen incorporation in Mo: catalytic hydrogenation vs. hydrogenolysis
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The reactions of (eta(6)-C6H6)RuCl2 and (eta(6)-p-cymene)RuCl2 With hydrogen in the presence of the water-soluble phosphines tppts (meta-trisulfonated triphenylphosphine) and pta (1,3,5-triaza-7-phosphaadamantane) afforded as the main species [(e ...
The hydrogenation of benzene and other arene substrates under biphasic conditions is evaluated using the catalyst precursor Ru(eta(6)-C10H14)(pta)Cl-2 (pta = 1,3,5-triaza-7-phosphaadamantane) immobilised in water and 1-alkyl-3-methylimidazolium tetrafluoro ...
Optimal conditions for chlorotris(triphenylphosphine)rhodium(I) (Wilkinson's catalyst) catalyzed selective satn. of a double bond in the presence of a nitro function are developed. Aryl iodide and benzyl ether are also tolerated under these hydrogenation c ...
Hydrogenation of 2-butyne-1,4-diol catalyzed by Pd nanoparticles on activated carbon fibers (ACFs) was studied. The ACF support in the form of woven fabrics provides the basis for structured catalytic fixed beds. In the present study, this catalyst was int ...
CO2 hydrogenation over catalysts is a potentially exciting method to produce fuels while closing the CO2 cycle and mitigating global warming. The mechanism of this process has been controversial due to the difficulty in clearly identifying the species pres ...
CO2 hydrogenation over catalysts is a potentially exciting method to produce fuels while closing the CO2 cycle and mitigating global warming. The mechanism of this process has been controversial due to the difficulty in clearly identifying the species pres ...
The lithium enolate of (-)-6-endo-chloro-5-exo-(phenyl-seleno)-7-oxabicyclo[2.2.1]heptan-2-one ((-)-4) added to (+)-(3aR, 4aR,7aR,7bS)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2, 3-d]isoxazole-3-carbaldehyde ((+)-5) giving a major aldol (+) ...
