Deciphering crystal packing effects in the spin crossover of six [Fe-II(2-pic)(3)]Cl-2 solvatomorphs
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The ternary sulfide Ag7TaS6 displays high Ag-ion conductivity at ambient temperature, and the framework TaS6 and Ag ions can be respectively regarded as the host structure and guest ions. Two low-temperature phases, i.e. Ag7TaS6 II and Ag7TaS6 III, were fo ...
The incommensurately modulated twinned crystal structure of lazurite from the Baikal region is presented for the first time. The orthorhombic structure was solved in a pseudo cubic unit cell, a(cub) = 9.077(1) Angstrom, and in the (3 + 2)D superspace group ...
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Using electrodeposition from a bath of molten fluorides, single crystals of tetragonal beta-tantalum have been obtained for the first time at normal pressure. The unit-cell parameters are a = 10.211 (3), c = 5.3064 (10) Angstrom, space group P (4) over bar ...
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Herein is reported the synthesis and characterization of a [RR1P-PR]-type radical, (I) (R = 2,4,6-tBu3C6H2; R' = CH3). I is stable in the solid state at temps. below -30 Deg. Suitable crystals of I were unobtainable, but a combination of EPR expts. and the ...
